{"id":"W2061610258","doi":"10.1021/ic034934a","title":"Palladium(II) Complexes of Bowls, Pinwheels, Cages, and <i>N,C,N</i>-Pincers of Starburst Ligands 1,3,5-Tris(di-2-pyridylamino)benzene and 2,4,6-Tris(di-2-pyridylamino)-1,3,5-triazene","year":2004,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Palladium; Tris; Steric effects; Benzene; Chelation; Triazene; Crystallography; Medicinal chemistry; Stereochemistry; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004009875,0.0009400079,0.001740579,0.0001731946,0.0003431512,0.0000993852,0.0009467184,0.0005833677,0.003562992],"category_scores_gemma":[0.0002949405,0.0009818336,0.0003880538,0.0007470321,0.0008532547,0.0002473191,0.0008540546,0.0005733564,0.000007088272],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000327611,"about_ca_system_score_gemma":0.0004306525,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006540028,"about_ca_topic_score_gemma":0.00007960448,"domain_scores_codex":[0.9952238,0.00002822728,0.001648473,0.001303932,0.0009054347,0.0008901512],"domain_scores_gemma":[0.9963579,0.0003025808,0.0009900394,0.001534731,0.0002890414,0.0005256923],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001383179,0.0004900564,0.003077226,0.001622543,0.0005495275,0.00002674225,0.0007356151,0.00002375943,0.9890146,0.0001062199,0.0001329016,0.004082494],"study_design_scores_gemma":[0.003265818,0.00009890345,0.004893436,0.0003849402,0.0005757768,0.0001349141,0.00119718,0.00004663388,0.9839265,0.0003009496,0.004213313,0.0009616865],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.984604,0.01057409,0.00005502135,0.0004088164,0.00008289364,0.000194295,0.0006763734,0.000159487,0.003245016],"genre_scores_gemma":[0.9947181,0.002986537,0.0002240007,0.00003838597,0.0003577961,0.00002036941,0.0002413349,0.0001494268,0.001264086],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01011406,"threshold_uncertainty_score":0.9992632,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008665581476632826,"score_gpt":0.2021326014844001,"score_spread":0.1934670200077673,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}