{"id":"W2061610258","doi":"10.1021/ic034934a","title":"Palladium(II) Complexes of Bowls, Pinwheels, Cages, and <i>N,C,N</i>-Pincers of Starburst Ligands 1,3,5-Tris(di-2-pyridylamino)benzene and 2,4,6-Tris(di-2-pyridylamino)-1,3,5-triazene","year":2004,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":29,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Palladium; Tris; Steric effects; Benzene; Chelation; Triazene; Crystallography; Medicinal chemistry; Stereochemistry; Inorganic chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005730223,0.0003529221,0.0002677934,0.0001618215,0.0001502974,0.0003878096,0.0005865783,0.0003624441,0.0009895284],"category_scores_gemma":[0.0001924933,0.0001904638,0.0001096377,0.0002269525,0.0002358505,0.000304395,0.0004616846,0.0003033344,0.0002812478],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005077447,"about_ca_system_score_gemma":0.0001424795,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009755181,"about_ca_topic_score_gemma":0.001652969,"domain_scores_codex":[0.9998866,0.00001464682,0.000006522591,0.00003830367,0.00002569106,0.00002810621],"domain_scores_gemma":[0.9999428,0.000007392684,0.000016934,0.0000066689,0.000007634762,0.00001856901],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008181367,0.00007742391,0.0006191551,0.0004795997,0.00006152978,0.0001478184,0.0001033502,0.001658916,0.9820119,0.001732336,0.0008366969,0.01145303],"study_design_scores_gemma":[0.00006369862,0.0005486854,0.0008963164,0.00001118984,0.000025231,0.0002021978,0.00005457646,0.001580573,0.9859234,0.0001251667,0.01055226,0.00001665633],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9893665,0.002338705,0.003087438,0.0000710458,0.00003846423,0.00004236706,0.0001251391,0.0002541694,0.004676188],"genre_scores_gemma":[0.9922647,0.0007784813,0.002591299,0.00006968814,0.000004903273,0.00002545696,0.0002484403,0.00003358675,0.003983419],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009895284,"threshold_uncertainty_score":0.003683925,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008665581476632826,"score_gpt":0.2021326014844001,"score_spread":0.1934670200077673,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}