{"id":"W2061632606","doi":"10.1002/chem.200903483","title":"Cyclizations via Frustrated Lewis Pairs: Lewis Acid Induced Intramolecular Additions of Amines to Olefins and Alkynes","year":2010,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":127,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Intramolecular force; Frustrated Lewis pair; Lewis acids and bases; Chemistry; Ring (chemistry); Organic chemistry; Stereochemistry; Medicinal chemistry; Computational chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0002086243,0.0004012283,0.0003560016,0.00006224359,0.0003042946,0.0001831338,0.0005618411,0.0001960387,0.007939977],"category_scores_gemma":[0.0005302462,0.0004141925,0.0001488139,0.0003210403,0.0002247725,0.0001553497,0.0001801121,0.00113111,0.00004130947],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003573574,"about_ca_system_score_gemma":0.000115347,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000004839897,"about_ca_topic_score_gemma":0.000005495607,"domain_scores_codex":[0.9980153,0.00004346384,0.000724618,0.0004605253,0.0003145737,0.0004415026],"domain_scores_gemma":[0.9980007,0.00005064948,0.000346978,0.0005894592,0.0003123864,0.0006998599],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001579501,0.0001954064,0.0009962016,0.0001464038,0.00008431522,0.0001366418,0.0001912787,0.00000482484,0.9942331,0.000007753471,0.001304457,0.002683852],"study_design_scores_gemma":[0.0007753003,0.00002759829,0.001156521,0.0001122526,0.00008423708,0.001097482,0.0003358384,0.00008718473,0.9925387,0.000048229,0.003305976,0.000430698],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9894131,0.00007210097,0.0003526248,0.0004514061,0.0001201467,0.00005086935,0.0001645382,0.0001282828,0.009246896],"genre_scores_gemma":[0.9975781,0.00005324164,0.0007924231,0.0001351951,0.0007626286,0.000005275841,0.0001229914,0.0001039017,0.0004462462],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00880065,"threshold_uncertainty_score":0.999831,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00944221909463571,"score_gpt":0.2140186242305024,"score_spread":0.2045764051358667,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}