{"id":"W2061869390","doi":"10.1021/om2000597","title":"Design, Synthesis, and Characterization of Functionalized Silepins: High Quantum Yield Blue Emitters","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Engineering and Physical Sciences Research Council; National Research Council Canada; National Science Council","keywords":"Chemistry; HOMO/LUMO; Transmetalation; Quantum yield; Atomic orbital; Cyclic voltammetry; Absorption spectroscopy; Absorption (acoustics); Molecular orbital; Photochemistry; Fluorescence; Crystallography; Computational chemistry; Molecule; Physical chemistry; Electron; Organic chemistry; Electrochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001815456,0.000364396,0.0002305709,0.0002060164,0.0001259238,0.0002718012,0.0003384531,0.0002190871,0.0009746227],"category_scores_gemma":[0.0002023705,0.0001617462,0.0001131354,0.0001770017,0.0001620341,0.0003316139,0.000165048,0.0003610756,0.0003263431],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005252603,"about_ca_system_score_gemma":0.0001850762,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003447983,"about_ca_topic_score_gemma":0.000888063,"domain_scores_codex":[0.9999098,0.00001068539,0.000006860468,0.00002543936,0.00003296682,0.00001414966],"domain_scores_gemma":[0.9998908,0.00001753298,0.00003197293,0.0000107563,0.00002344297,0.00002550398],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000029799,0.0000164073,0.00007503229,0.00003571006,0.000003423225,0.00002781856,0.00001223224,0.000278732,0.9972743,0.0001705698,0.00002873253,0.00204707],"study_design_scores_gemma":[0.00001000928,0.0001291927,0.0004727567,0.000002175731,0.000004645296,0.00005382616,0.000004505192,0.000716404,0.9973181,0.00001797127,0.001267121,0.000003369545],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9805754,0.001080091,0.01336845,0.00005786249,0.0000145575,0.0001528828,0.000548501,0.0001279182,0.004074273],"genre_scores_gemma":[0.9624514,0.00144902,0.03120526,0.00005865553,0.00001283517,0.0001320421,0.0006028466,0.0000568689,0.004031142],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009746227,"threshold_uncertainty_score":0.003811061,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03040271864256137,"score_gpt":0.2034995168288827,"score_spread":0.1730967981863214,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}