{"id":"W2061869390","doi":"10.1021/om2000597","title":"Design, Synthesis, and Characterization of Functionalized Silepins: High Quantum Yield Blue Emitters","year":2011,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":43,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Engineering and Physical Sciences Research Council; National Research Council Canada; National Science Council","keywords":"Chemistry; HOMO/LUMO; Transmetalation; Quantum yield; Atomic orbital; Cyclic voltammetry; Absorption spectroscopy; Absorption (acoustics); Molecular orbital; Photochemistry; Fluorescence; Crystallography; Computational chemistry; Molecule; Physical chemistry; Electron; Organic chemistry; Electrochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001261648,0.000266595,0.00037622,0.0000706639,0.00007697329,0.00002541248,0.0002280317,0.0002451924,0.01578185],"category_scores_gemma":[0.0001689835,0.0002681747,0.00007091464,0.0002043509,0.000151967,0.0001664385,0.00008579427,0.0001582936,0.00004242906],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004045441,"about_ca_system_score_gemma":0.0000675546,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002988288,"about_ca_topic_score_gemma":0.000001101085,"domain_scores_codex":[0.9986925,0.00002316396,0.0004280289,0.0003816786,0.0002215451,0.0002530451],"domain_scores_gemma":[0.9989641,0.0001467042,0.0002574521,0.0004068037,0.0000855863,0.0001393756],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000714223,0.0001553655,0.002463268,0.0001986005,0.0001053428,0.000004437107,0.0003632108,3.096689e-7,0.9952916,0.0002918713,0.00003087202,0.00102368],"study_design_scores_gemma":[0.0003072267,0.00002080713,0.006331629,0.00005677978,0.0001106437,0.000015395,0.0001265,0.00002775149,0.9918793,0.00006804371,0.0007734789,0.0002823739],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970385,0.0001255954,0.001418481,0.0000837454,0.000149077,0.00007850433,0.00005892625,0.0001180781,0.0009291144],"genre_scores_gemma":[0.9981256,0.0003547142,0.0005101369,0.0001208171,0.0001242192,0.00002170939,0.00006259174,0.0000633485,0.0006169184],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01573942,"threshold_uncertainty_score":0.9999771,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03040271864256137,"score_gpt":0.2034995168288827,"score_spread":0.1730967981863214,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}