{"id":"W2061952914","doi":"10.1002/aoc.379","title":"Hypervalent selenium compounds containing N → Se intramolecular interactions: synthesis, characterization and X‐ray structures of [2‐(Me<sub>2</sub>NCH<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>]SeS(S)PR<sub>2</sub> (R = Ph, O<sup>i</sup>Pr)","year":2002,"lang":"en","type":"article","venue":"Applied Organometallic Chemistry","topic":"Organoselenium and organotellurium chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Hypervalent molecule; Selenium; Denticity; Intramolecular force; Crystallography; Crystal structure; Monomer; Stereochemistry; X-ray crystallography; X-ray; Molecule; Diffraction; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009298875,0.0002212959,0.0001537615,0.00009252439,0.0001078592,0.0002186613,0.0001688283,0.0002517231,0.001119077],"category_scores_gemma":[0.0001572711,0.0001246553,0.00005986223,0.000106958,0.0002013444,0.0001592729,0.0001628948,0.0001485757,0.0002852559],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001806486,"about_ca_system_score_gemma":0.0001419762,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003015205,"about_ca_topic_score_gemma":0.0007783226,"domain_scores_codex":[0.9999393,0.00001773001,0.000004454474,0.000009742632,0.00001753137,0.0000112289],"domain_scores_gemma":[0.9999471,0.00001030275,0.00001484801,0.000006903095,0.00001080232,0.000009944818],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000102906,0.00001202253,0.0001650708,0.00003618385,0.000005904008,0.00006076147,0.00001356023,0.0001122919,0.9978706,0.000113432,0.00004929445,0.001457996],"study_design_scores_gemma":[0.00002460493,0.0002777322,0.0010023,0.000003246238,0.00001108413,0.0001463638,0.00001439381,0.0002272835,0.9963543,0.00004538206,0.001890338,0.000003031569],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9970848,0.000563639,0.0007886742,0.00002674878,0.000004651594,0.00001208712,0.00007324362,0.00002843445,0.001417801],"genre_scores_gemma":[0.9948089,0.0004212215,0.001615805,0.00003115604,0.000004161509,0.00001404275,0.0002816981,0.00001265208,0.002810309],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001119077,"threshold_uncertainty_score":0.003743708,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02593863783180099,"score_gpt":0.2714637492003775,"score_spread":0.2455251113685765,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}