{"id":"W2061952914","doi":"10.1002/aoc.379","title":"Hypervalent selenium compounds containing N → Se intramolecular interactions: synthesis, characterization and X‐ray structures of [2‐(Me<sub>2</sub>NCH<sub>2</sub>)C<sub>6</sub>H<sub>4</sub>]SeS(S)PR<sub>2</sub> (R = Ph, O<sup>i</sup>Pr)","year":2002,"lang":"en","type":"article","venue":"Applied Organometallic Chemistry","topic":"Organoselenium and organotellurium chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Hypervalent molecule; Selenium; Denticity; Intramolecular force; Crystallography; Crystal structure; Monomer; Stereochemistry; X-ray crystallography; X-ray; Molecule; Diffraction; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","research_integrity"],"consensus_categories":["metaepi_narrow","research_integrity"],"category_scores_codex":[0.001178779,0.002890197,0.002968799,0.0005968325,0.001393631,0.0004231891,0.001714591,0.002915585,0.0008858326],"category_scores_gemma":[0.0006239434,0.003329741,0.0009048525,0.00199561,0.001779059,0.00081566,0.001030933,0.004352437,0.0004587207],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001024003,"about_ca_system_score_gemma":0.0005647029,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000007633401,"about_ca_topic_score_gemma":0.00001267356,"domain_scores_codex":[0.9884591,0.0006011037,0.003279611,0.003347469,0.001487978,0.002824762],"domain_scores_gemma":[0.9919997,0.001474211,0.002167382,0.001990593,0.0006918299,0.001676229],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000940019,0.00170959,0.000836971,0.002182276,0.002203546,0.0001754853,0.00188497,0.000406518,0.9695465,0.00005403358,0.001159803,0.01890032],"study_design_scores_gemma":[0.004180487,0.0001592062,0.00118573,0.0003034549,0.002462086,0.0007026866,0.001024278,0.001318918,0.9825327,0.0001646345,0.002866819,0.003098959],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9916054,0.002004492,0.0004995687,0.0006683556,0.001033624,0.001759004,0.0009200118,0.0008581243,0.0006513936],"genre_scores_gemma":[0.9845606,0.008657708,0.0001398431,0.001417218,0.002025533,0.0005293674,0.001925315,0.000694687,0.00004968987],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01580136,"threshold_uncertainty_score":0.9999064,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02593863783180099,"score_gpt":0.2714637492003775,"score_spread":0.2455251113685765,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}