{"id":"W2062002171","doi":"10.1039/c1cc11737h","title":"Intercepting low oxidation state main group hydrides with a nucleophilic N-heterocyclic olefin","year":2011,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":169,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"","keywords":"Olefin fiber; Chemistry; Nucleophile; Medicinal chemistry; Group (periodic table); Oxidation state; Lewis acids and bases; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007758219,0.0002896164,0.0001351574,0.0001027073,0.0001146552,0.0001923043,0.0002353666,0.0001944689,0.001051666],"category_scores_gemma":[0.0001227515,0.00009454426,0.0001118831,0.00006021888,0.0002460423,0.0002300803,0.0002763043,0.0002364943,0.0002332132],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001562664,"about_ca_system_score_gemma":0.00007693584,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003909375,"about_ca_topic_score_gemma":0.0007331707,"domain_scores_codex":[0.9999431,0.000006584391,0.000001991431,0.00001253776,0.00001530505,0.00002041268],"domain_scores_gemma":[0.9999447,0.00001499643,0.00001655666,0.000007316221,0.000006960784,0.000009522806],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008633027,0.000006963554,0.0001395382,0.00003695891,0.000004091434,0.00004008808,0.00002523441,0.00008519457,0.9975085,0.0002281369,0.00005794824,0.001781008],"study_design_scores_gemma":[0.000004201282,0.00009456559,0.0003383154,9.904312e-7,0.00000290654,0.00005657496,0.000007007444,0.0001941843,0.9985862,0.00002059716,0.0006928996,0.000001671089],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9919544,0.0004434166,0.003182505,0.00003534224,0.0000151013,0.00002466023,0.000114316,0.0001081595,0.004122068],"genre_scores_gemma":[0.9977964,0.0001926508,0.0007139522,0.000009181734,0.000004926087,0.000004655464,0.00007868483,0.00001567371,0.001183852],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001051666,"threshold_uncertainty_score":0.003518164,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02721744907380031,"score_gpt":0.2332116546767158,"score_spread":0.2059942056029155,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}