{"id":"W2062129726","doi":"10.1039/b718918d","title":"Synthesis and dehydrocoupling reactivity of iron and ruthenium phosphine–borane complexes","year":2008,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Hydrogen Storage and Materials","field":"Materials Science","cited_by":35,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Engineering and Physical Sciences Research Council; University of Toronto; European Commission; Royal Society","keywords":"Phosphine; Borane; Chemistry; Reactivity (psychology); Catalysis; Ruthenium; Adduct; Medicinal chemistry; Stoichiometry; Yield (engineering); Organic chemistry; Materials science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002141381,0.000126745,0.0002798158,0.00005865915,0.0002716231,0.00002124893,0.00006802929,0.00006562106,0.0003594522],"category_scores_gemma":[0.00001804444,0.0001179175,0.00003459569,0.0000781547,0.0002221598,0.0002364681,0.000008025404,0.00005823666,0.00001153181],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001272395,"about_ca_system_score_gemma":0.00002403892,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009050985,"about_ca_topic_score_gemma":0.00005736588,"domain_scores_codex":[0.9991863,0.00004255183,0.0002273488,0.0002381105,0.000131757,0.0001739016],"domain_scores_gemma":[0.9995034,0.0001214179,0.00008327559,0.0001751216,0.00002960159,0.00008715049],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004159996,0.00006209634,0.00006005265,0.00006787657,0.000006831956,0.000006436464,0.0006214232,0.00005769601,0.9982746,0.00003044795,0.000007910691,0.0007630606],"study_design_scores_gemma":[0.0001869128,0.00003498009,0.0009026955,0.00002436453,0.00005039975,0.00009828357,0.00006712147,0.0001387514,0.99774,0.000061203,0.0005688682,0.0001263599],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.992483,0.0002433936,0.006619906,0.0000776658,0.0001311025,0.0001357627,0.0001507215,0.00006212258,0.00009629987],"genre_scores_gemma":[0.9983706,0.0003952087,0.001095308,0.00001645898,0.00002746914,0.00002351814,0.000002821283,0.00001463218,0.00005393187],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005887626,"threshold_uncertainty_score":0.4808537,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02020083703988404,"score_gpt":0.2380555298850126,"score_spread":0.2178546928451286,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}