{"id":"W2062213669","doi":"10.1016/j.inoche.2007.08.012","title":"Synthesis and characterization of 1-(3,5-di-tert-butyl)pyrazolyldiphenylphosphine and its gold(I) complex","year":2007,"lang":"en","type":"article","venue":"Inorganic Chemistry Communications","topic":"Catalytic Alkyne Reactions","field":"Chemistry","cited_by":2,"is_retracted":false,"has_abstract":false,"ca_institutions":"Saint Mary's University; Mount Saint Vincent University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Denticity; Ligand (biochemistry); Chemistry; Pyrazole; Medicinal chemistry; Stereochemistry; Crystal structure; Crystallography; Receptor","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002047073,0.000216566,0.0003035209,0.00004032062,0.0001910437,0.0000361432,0.0005770905,0.0001760477,0.0006442346],"category_scores_gemma":[0.0002687724,0.000251311,0.00005296321,0.0002475714,0.0002915321,0.0001528202,0.0005585959,0.0002847328,0.000009180394],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001077272,"about_ca_system_score_gemma":0.00006314628,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005436371,"about_ca_topic_score_gemma":0.00002462837,"domain_scores_codex":[0.9987521,0.000007873225,0.0005486943,0.0002833225,0.0001710737,0.0002368924],"domain_scores_gemma":[0.9974384,0.0004948312,0.0003178538,0.001424788,0.0001642747,0.0001598521],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001091014,0.0001440851,0.001448964,0.0001975987,0.00006623343,9.411798e-7,0.0002476414,6.373872e-8,0.9949908,0.0002254348,0.00002165002,0.00264568],"study_design_scores_gemma":[0.0002927756,0.000003448507,0.01430538,0.00009087583,0.0001144089,0.0001179381,0.000307962,0.0004276287,0.9799487,0.00003750476,0.004111992,0.0002414102],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9891172,0.0006747097,0.00009357417,0.0007966184,0.00001437459,0.00008686297,0.0002000388,0.0001142171,0.008902405],"genre_scores_gemma":[0.9973859,0.001114905,0.0002247397,0.00002502762,0.00005500527,0.00001950945,0.0003778879,0.00003971111,0.0007572789],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01504212,"threshold_uncertainty_score":0.9999939,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02276865874919284,"score_gpt":0.2557225250645059,"score_spread":0.232953866315313,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}