{"id":"W2062365230","doi":"10.1039/c1dt11595b","title":"Oxygenextrusion from amidate ligands to generate terminal TaO units under reducing conditions. How to successfully use amidate ligands in dinitrogen coordination chemistry","year":2011,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":19,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Tantalum; Chemistry; Metathesis; Ligand (biochemistry); Salt (chemistry); Salt metathesis reaction; Stereoselectivity; Medicinal chemistry; Stereochemistry; Organic chemistry; Catalysis; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001539905,0.000393104,0.0004344708,0.0002882707,0.0003572061,0.0002400411,0.0004169121,0.000214021,0.01058913],"category_scores_gemma":[0.00005114187,0.000431392,0.000151081,0.001175076,0.00006046672,0.0005335698,0.00004432673,0.0002601722,0.00006553882],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002288011,"about_ca_system_score_gemma":0.0001124511,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001601306,"about_ca_topic_score_gemma":0.0006653807,"domain_scores_codex":[0.9978641,0.00002582313,0.0005249634,0.0007825493,0.0003187587,0.0004837707],"domain_scores_gemma":[0.9985059,0.00008699407,0.0001536535,0.0007166034,0.0001972017,0.0003396738],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007801822,0.0002247912,0.0005222258,0.00003837065,0.0001322251,0.00002040957,0.00103333,0.0004947266,0.9936573,0.00001262316,0.00009416761,0.00369182],"study_design_scores_gemma":[0.0004910409,0.0000246251,0.007619157,0.000101649,0.0002150189,0.00001458694,0.0008068216,0.0007421811,0.9876814,0.00006311016,0.001718715,0.0005216496],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9920716,0.00002705719,0.004774202,0.0007681739,0.0001048374,0.0001644495,0.001273269,0.0001473786,0.000669073],"genre_scores_gemma":[0.9931803,0.00004402092,0.0006892941,0.0001447457,0.0001403512,0.0001614385,0.001121694,0.00007164267,0.00444656],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01052359,"threshold_uncertainty_score":0.9998138,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03973387959551437,"score_gpt":0.238141478525334,"score_spread":0.1984075989298196,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}