{"id":"W2062420697","doi":"10.1139/cjc-2014-0440","title":"Theoretical study of the gas-phase decomposition of Pb[(C<sub>6</sub>H<sub>5</sub>)<sub>2</sub>PSSe]<sub>2</sub> single-source precursor for the chemical vapour deposition of binary and ternary lead chalcogenides","year":2014,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chalcogenide Semiconductor Thin Films","field":"Engineering","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Council for Tertiary Education","keywords":"Chemistry; Ternary operation; Chemical vapor deposition; Kinetic energy; Deposition (geology); Singlet state; Decomposition; Density functional theory; Physical chemistry; Analytical Chemistry (journal); Computational chemistry; Organic chemistry; Atomic physics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0009596715,0.0007174026,0.001038021,0.0002598492,0.0002649928,0.0000900364,0.0009568686,0.0005354929,0.00001084189],"category_scores_gemma":[0.000556386,0.0006259286,0.0006067525,0.0004262612,0.0008302071,0.000297228,0.0001268086,0.001135551,0.000002484508],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004749513,"about_ca_system_score_gemma":0.0003960945,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004885988,"about_ca_topic_score_gemma":0.0002170291,"domain_scores_codex":[0.9960075,0.0002178395,0.00163195,0.0005485053,0.0007206898,0.0008735327],"domain_scores_gemma":[0.996066,0.0007691792,0.0009783406,0.000844012,0.0005346902,0.0008078117],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003675904,0.0003720702,0.0003298324,0.0006675207,0.0005319518,0.00005847687,0.001332444,0.001222939,0.9873533,0.00002601182,0.0004171084,0.007320736],"study_design_scores_gemma":[0.002935032,0.0005404634,0.0004029596,0.0008599871,0.0006541945,0.001290693,0.0009966834,0.004951457,0.9863859,0.0003947949,0.00001755225,0.000570297],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9960721,0.001362321,0.0007130564,0.0002677727,0.0004752023,0.0007532203,0.0002235991,0.00004862142,0.00008416016],"genre_scores_gemma":[0.9987566,0.0001258883,0.0001347199,0.00007260016,0.000637597,0.00004078108,0.0000459946,0.0001845586,0.000001297192],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006750439,"threshold_uncertainty_score":0.9996192,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009624896899085267,"score_gpt":0.2131019390673072,"score_spread":0.2034770421682219,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}