{"id":"W2062423693","doi":"10.1139/v05-165","title":"The mechanisms of hydrolysis of alkyl <i>N</i>-alkylthioncarbamate esters at 100 °C","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Hydrolysis; Reaction rate constant; Catalysis; Conjugate acid; Medicinal chemistry; Hydrolysis constant; Acid catalysis; Alkyl; Base (topology); Inorganic chemistry; Organic chemistry; Kinetics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.000342952,0.000210631,0.0004129261,0.00005425654,0.0001249936,0.00002608458,0.0006916019,0.0002338615,0.002033855],"category_scores_gemma":[0.0003196527,0.00017651,0.0003612656,0.0001676207,0.0002029188,0.0001017108,0.00004173849,0.0004062651,0.000008310485],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005428002,"about_ca_system_score_gemma":0.0007854307,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002770291,"about_ca_topic_score_gemma":0.0006136644,"domain_scores_codex":[0.998028,0.00001260778,0.0009185141,0.0001709105,0.0004672563,0.0004026421],"domain_scores_gemma":[0.9972689,0.0001975979,0.00101844,0.0004804468,0.0003129552,0.0007216219],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000417632,0.00001787752,0.00006904459,0.0001042893,0.0001152251,0.00002134586,0.0001265285,0.00009326971,0.9957163,0.00006793918,0.001156374,0.002470012],"study_design_scores_gemma":[0.000486385,0.00001312344,0.000006523847,0.0001353285,0.00007667462,0.0002715034,0.0003110643,0.00008286823,0.9774922,0.0008384007,0.02013691,0.0001490862],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9820014,0.000866712,0.0001151032,0.001011887,0.0001277391,0.00003134889,0.00005707133,0.000009570702,0.01577917],"genre_scores_gemma":[0.9966172,0.00007513124,0.000411873,0.00008877942,0.0002084434,0.000002225808,0.000007162402,0.00003364656,0.002555559],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01898054,"threshold_uncertainty_score":0.9988784,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006666756377034076,"score_gpt":0.2011468339454514,"score_spread":0.1944800775684173,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}