{"id":"W2062440472","doi":"10.1016/j.tetlet.2008.03.098","title":"Acceleration of bromide mediated benzoylperoxide oxidations of secondary alcohols in aqueous organic solvents","year":2008,"lang":"en","type":"article","venue":"Tetrahedron Letters","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":false,"ca_institutions":"Cape Breton University; University of Guelph","funders":"","keywords":"Chemistry; Alcohol oxidation; Cyclohexanol; Aqueous solution; Acetonitrile; Organic chemistry; Bromide; Reagent; Solvent; Alcohol; Halogenation; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002609747,0.0004808146,0.0003157116,0.0001809309,0.0001528905,0.000220829,0.0003206967,0.0003413842,0.001907333],"category_scores_gemma":[0.0002885594,0.0002159492,0.0002170967,0.0001579653,0.0002044016,0.0004041352,0.0003610957,0.0005876085,0.0006307449],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002457488,"about_ca_system_score_gemma":0.0002147642,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007200869,"about_ca_topic_score_gemma":0.00127325,"domain_scores_codex":[0.9997669,0.00003197979,0.00001172666,0.0000276908,0.00006875839,0.0000930025],"domain_scores_gemma":[0.9998842,0.00002806426,0.00003062437,0.00001269666,0.00002463783,0.00001971342],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002215855,0.00002416035,0.00007066924,0.00009774262,0.000007132923,0.00008330039,0.00008642703,0.0000827917,0.9958228,0.00017682,0.0001349226,0.003191645],"study_design_scores_gemma":[0.00001311721,0.0001134642,0.0001582649,0.000002570309,0.000004277605,0.00002786971,0.0000115784,0.0001837015,0.998931,0.00002105266,0.0005307921,0.000002299686],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9861902,0.001232935,0.006804818,0.0001762751,0.00008624323,0.00005026552,0.0001209686,0.000171303,0.00516685],"genre_scores_gemma":[0.9953132,0.0007842127,0.0009993382,0.00002318169,0.00001192961,0.00001205457,0.00006850551,0.0000253756,0.002762193],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001907333,"threshold_uncertainty_score":0.006380618,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01912438365630632,"score_gpt":0.2299743437632967,"score_spread":0.2108499601069904,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}