{"id":"W2062540230","doi":"10.1021/es030546w","title":"Simulating Organic Aerosol Formation during the Photooxidation of Toluene/NO<i><sub>x</sub></i>Mixtures:  Comparing the Equilibrium and Kinetic Assumption","year":2004,"lang":"en","type":"article","venue":"Environmental Science & Technology","topic":"Atmospheric chemistry and aerosols","field":"Earth and Planetary Sciences","cited_by":53,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Aerosol; Toluene; Chemistry; Particulates; Ozone; NOx; Kinetic scheme; Kinetic energy; Environmental chemistry; Thermodynamics; Physical chemistry; Organic chemistry; Combustion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003470208,0.0005047072,0.0003525536,0.0002175291,0.000409482,0.0005232897,0.0006306364,0.0007758914,0.0009985066],"category_scores_gemma":[0.0005682955,0.0002228046,0.0005618666,0.000214588,0.0002319455,0.0005901339,0.0002650819,0.0004221928,0.0001363584],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001539759,"about_ca_system_score_gemma":0.0007401349,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.02595841,"about_ca_topic_score_gemma":0.01464484,"domain_scores_codex":[0.9999025,0.00001887737,0.000006921627,0.00002236175,0.0000262921,0.00002297449],"domain_scores_gemma":[0.9996532,0.0002082204,0.00004028092,0.00001845082,0.00005427219,0.00002558605],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"simulation_or_modeling","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.0002294401,0.0002374582,0.007326918,0.00008246699,0.00002640629,0.0001061096,0.00004860548,0.9516711,0.03610478,0.0005159838,0.0001161024,0.003534568],"study_design_scores_gemma":[0.00003449696,0.0001533425,0.001966545,0.000002574274,0.00001021005,0.000009621814,0.00002690941,0.9778526,0.01971915,0.00009583813,0.000120273,0.000008535404],"study_design_candidate":"simulation_or_modeling","study_design_consensus":"simulation_or_modeling","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9923409,0.00007768126,0.005090028,0.00004247324,0.00001349077,0.00006494896,0.0003140812,0.0000988372,0.001957508],"genre_scores_gemma":[0.9964429,0.00007590084,0.002730421,0.00001322227,0.000003119981,0.00004185906,0.0001651427,0.00001964437,0.0005079739],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02595841,"threshold_uncertainty_score":0.05161464,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005304455327012773,"score_gpt":0.1783197170638823,"score_spread":0.1730152617368695,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}