{"id":"W2063079817","doi":"10.1002/macp.200500378","title":"Kinetic Behavior of Atom Transfer Radical Polymerization of Dimethacrylates","year":2006,"lang":"en","type":"article","venue":"Macromolecular Chemistry and Physics","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":45,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Polymerization; Atom-transfer radical-polymerization; Polymer chemistry; Radical polymerization; Chemistry; Reaction rate constant; Ethylene glycol; Kinetics; Living free-radical polymerization; Photochemistry; Materials science; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0004649881,0.0003532771,0.0002391304,0.0002922793,0.00009242228,0.0003443906,0.0002901097,0.0003018343,0.002047641],"category_scores_gemma":[0.0007994808,0.0001834502,0.0002194921,0.000182246,0.0001363644,0.0005347747,0.0001119047,0.0006181205,0.0006526485],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004325768,"about_ca_system_score_gemma":0.0001701979,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004560055,"about_ca_topic_score_gemma":0.0002573296,"domain_scores_codex":[0.9997905,0.00003009666,0.00001278609,0.00006566722,0.00006377031,0.0000372419],"domain_scores_gemma":[0.9995222,0.0002216416,0.00009943537,0.00003068542,0.00008248955,0.00004354703],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001781245,0.00003828768,0.0003504415,0.00007668619,0.00001321992,0.00003048865,0.00004559528,0.000727357,0.9944283,0.0002010051,0.00005264467,0.003857735],"study_design_scores_gemma":[0.000006070052,0.0001233881,0.0007615323,0.000004588606,0.000006215783,0.00002339648,0.000006357418,0.004525908,0.9940352,0.00003750875,0.0004633077,0.000006491752],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9846132,0.001380577,0.01093812,0.00006658636,0.00002547381,0.00004421076,0.0004089433,0.0002546945,0.002268176],"genre_scores_gemma":[0.9926566,0.0006187945,0.003357014,0.00001931757,0.000005593513,0.00003444291,0.0003531524,0.00003976964,0.002915297],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002047641,"threshold_uncertainty_score":0.006850004,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004026427257871112,"score_gpt":0.1989813884338615,"score_spread":0.1949549611759904,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}