{"id":"W2063460132","doi":"10.1039/c3dt33070b","title":"Structural variation in ethylenediamine and -diphosphine adducts of (2,6-Me2C6H3S)2Pb: a single crystal X-ray diffraction and 207Pb solid-state NMR spectroscopy study","year":2013,"lang":"en","type":"article","venue":"Dalton Transactions","topic":"Advanced NMR Techniques and Applications","field":"Chemistry","cited_by":25,"is_retracted":false,"has_abstract":true,"ca_institutions":"Mount Allison University; University of Saskatchewan; University of Windsor","funders":"","keywords":"Chemistry; Trigonal bipyramidal molecular geometry; Ethylenediamine; Denticity; Crystallography; Adduct; Nuclear magnetic resonance spectroscopy; Crystal structure; Metal; Ligand (biochemistry); Single crystal; Stereochemistry; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006189195,0.0001869064,0.0002386978,0.0001028999,0.0001334875,0.00003870383,0.0000719545,0.00008692095,0.0004264508],"category_scores_gemma":[0.00001299715,0.0001880256,0.00003189481,0.0001972529,0.00008011718,0.0004090711,0.0000103666,0.0002619976,0.000002001616],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007393273,"about_ca_system_score_gemma":0.00001821336,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001063644,"about_ca_topic_score_gemma":0.0004795353,"domain_scores_codex":[0.9989142,0.00001756651,0.000380502,0.0003440676,0.0001303,0.0002132926],"domain_scores_gemma":[0.9993631,0.00008054113,0.0001489646,0.0002457105,0.00007519816,0.00008645443],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003502721,0.0003913422,0.001066877,0.0000653319,0.00002696609,9.133806e-7,0.001214603,0.0007635279,0.9927003,0.00004575375,0.00001066137,0.003678726],"study_design_scores_gemma":[0.005660808,0.001043658,0.421628,0.0001963992,0.0002683422,0.00005762895,0.004302078,0.03364265,0.5207783,0.01011004,0.00102324,0.001288829],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9650573,0.00008521238,0.03381316,0.0002624072,0.00001947223,0.0004375359,0.0001013672,0.0000990495,0.0001245162],"genre_scores_gemma":[0.992979,0.0001382672,0.006383391,0.00001542968,0.00003424102,0.0001865662,0.00003375003,0.000025561,0.0002037623],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.471922,"threshold_uncertainty_score":0.7667461,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009926277918365072,"score_gpt":0.2640219731315505,"score_spread":0.2540956952131854,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}