{"id":"W2063565993","doi":"10.1021/la800963u","title":"Determination of the Surface Area of Pd and Nanometric Au Aggregates Supported on a Micrometric Solid Support by Thiol Adsorption and GC−MS","year":2008,"lang":"en","type":"article","venue":"Langmuir","topic":"Molecular Junctions and Nanostructures","field":"Engineering","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Guelph; Université de Sherbrooke","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Adsorption; Thiol; Chemistry; Palladium; Analytical Chemistry (journal); Solid surface; Mass spectrometry; Chromatography; Metal; Specific surface area; Materials science; Physical chemistry; Organic chemistry; Chemical physics; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002861905,0.0005813631,0.0004188133,0.001140465,0.000270489,0.0003265818,0.0005270919,0.0005031943,0.0006749224],"category_scores_gemma":[0.0004840583,0.0002628195,0.0002133049,0.0004668414,0.0003681758,0.0003074952,0.0002343075,0.0004839208,0.0003548783],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003246066,"about_ca_system_score_gemma":0.0001711116,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007887096,"about_ca_topic_score_gemma":0.001757083,"domain_scores_codex":[0.9995151,0.00003726379,0.00002380733,0.0001272587,0.0002636245,0.0000329191],"domain_scores_gemma":[0.9997448,0.00008400079,0.00004232402,0.00002752165,0.00007003031,0.00003126336],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002179578,0.00001148435,0.0002391075,0.00002325532,0.000006333987,0.00001165961,0.00001590569,0.00003909018,0.9975921,0.00003566534,0.00001920393,0.001984493],"study_design_scores_gemma":[0.00000366859,0.00009443902,0.002589398,0.000002218404,0.00001229913,0.00006912345,0.00002509035,0.001987423,0.9946016,0.00006949617,0.0005407789,0.000004462122],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9651541,0.002364705,0.02913976,0.0001042981,0.00006512782,0.00006666694,0.0006675172,0.0003012023,0.002136567],"genre_scores_gemma":[0.9579653,0.001442116,0.03640161,0.00007934345,0.00004407058,0.00009587035,0.0006317869,0.00003679367,0.003303119],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001140465,"threshold_uncertainty_score":0.002355218,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007679850209108028,"score_gpt":0.195501877785435,"score_spread":0.187822027576327,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}