{"id":"W2063718499","doi":"10.1021/ol050839p","title":"Solvent Effects on Hydrogen Abstraction Reactions from Lactones with Antioxidant Properties","year":2005,"lang":"en","type":"article","venue":"Organic Letters","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Hydrogen atom abstraction; Solvent; Abstraction; Antioxidant; Hydrogen; Organic chemistry; Combinatorial chemistry; Solvent effects; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003623128,0.0003874678,0.0002889299,0.0001552813,0.000193379,0.0002646433,0.0001617816,0.0001869506,0.001535974],"category_scores_gemma":[0.0008664622,0.0001474406,0.0001893487,0.0002094273,0.0002579612,0.0003448047,0.0001787366,0.000419102,0.000273681],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002603708,"about_ca_system_score_gemma":0.0001704495,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0008571935,"about_ca_topic_score_gemma":0.001035578,"domain_scores_codex":[0.9997924,0.00005580881,0.000009201698,0.00004179153,0.00004799879,0.00005275121],"domain_scores_gemma":[0.9993641,0.000328228,0.0001050939,0.00004100431,0.000108418,0.00005315904],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0008443914,0.00001922803,0.0003972921,0.00009219882,0.00001563158,0.00006775441,0.00007359119,0.0001478152,0.9954289,0.0000707364,0.00004765959,0.002794696],"study_design_scores_gemma":[0.00001181956,0.0002103089,0.000742208,0.000003261742,0.00001319446,0.00003321806,0.0000198039,0.0002882054,0.998148,0.00002566584,0.0004987461,0.000005624857],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938599,0.002953781,0.001959986,0.00004872549,0.00002886526,0.00002097048,0.000146233,0.00004914986,0.0009323764],"genre_scores_gemma":[0.9952635,0.001486551,0.001501206,0.00003389314,0.000016234,0.0000164742,0.0002357799,0.00002162236,0.001424841],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001535974,"threshold_uncertainty_score":0.005138397,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008699771140451071,"score_gpt":0.1933162330646156,"score_spread":0.1846164619241645,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}