{"id":"W2063718499","doi":"10.1021/ol050839p","title":"Solvent Effects on Hydrogen Abstraction Reactions from Lactones with Antioxidant Properties","year":2005,"lang":"en","type":"article","venue":"Organic Letters","topic":"Free Radicals and Antioxidants","field":"Chemistry","cited_by":37,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Chemistry; Hydrogen atom abstraction; Solvent; Abstraction; Antioxidant; Hydrogen; Organic chemistry; Combinatorial chemistry; Solvent effects; Computational chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004199339,0.0001998691,0.0001734419,0.00003689907,0.0001414981,0.00005209966,0.0001312194,0.00008187212,0.0007841519],"category_scores_gemma":[0.00001994858,0.0001486096,0.00006351845,0.00007559345,0.00005776994,0.0001804732,0.00001712752,0.0002523478,0.0004293267],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001335122,"about_ca_system_score_gemma":0.00002666165,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001598881,"about_ca_topic_score_gemma":0.00006670408,"domain_scores_codex":[0.9989376,0.00001477478,0.0001947434,0.000319105,0.0002667701,0.0002670202],"domain_scores_gemma":[0.9994267,0.00005536091,0.0001064497,0.0003059214,0.0000147854,0.00009080843],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004746785,0.0001403487,0.0006783644,0.00005127948,0.0000851032,0.00003310657,0.00007931428,0.00005538953,0.9955729,0.000008112042,0.001022463,0.002226111],"study_design_scores_gemma":[0.0005626321,0.00002920461,0.004385426,0.0002739815,0.00004548362,0.00002465154,0.00003418557,0.00008500298,0.9872214,0.000005516691,0.007107433,0.0002251344],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9921861,0.0001014259,0.00006259667,0.006751396,0.00008289221,0.0000712093,0.000008764158,0.0001783172,0.0005572503],"genre_scores_gemma":[0.99762,0.00004465462,0.000160936,0.001143984,0.0006925753,0.00001404631,0.00001365692,0.00004743073,0.0002627306],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008351591,"threshold_uncertainty_score":0.8585914,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008699771140451071,"score_gpt":0.1933162330646156,"score_spread":0.1846164619241645,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}