{"id":"W2063823107","doi":"10.1021/om049826q","title":"Reduction of Titanium(IV)-Phosphinimide Complexes:  Routes to Ti(III) Dimers, Ti(IV)-Metallacycles, and Ti(II) Species","year":2004,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":50,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"","keywords":"Chemistry; Titanium; Reduction (mathematics); Medicinal chemistry; Stereochemistry; Crystallography; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003222446,0.0006375542,0.001127127,0.0003305299,0.0003822339,0.0001549881,0.0007093281,0.0002439884,0.01761769],"category_scores_gemma":[0.000182513,0.0006319887,0.0003710723,0.001094884,0.0003958802,0.0003548097,0.0005975746,0.000306939,0.0001937724],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002900433,"about_ca_system_score_gemma":0.0001349327,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003506469,"about_ca_topic_score_gemma":0.0001109692,"domain_scores_codex":[0.9966138,0.00003110656,0.001009509,0.0009730592,0.0007078093,0.0006647423],"domain_scores_gemma":[0.9976826,0.0001109885,0.000424387,0.001174496,0.0001899739,0.0004175357],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008910321,0.0005296186,0.000370674,0.0002200639,0.0006414898,0.00001022552,0.001362978,0.00008697142,0.9811072,0.008523643,0.0004028162,0.006655266],"study_design_scores_gemma":[0.001961709,0.0002364418,0.007424894,0.000209749,0.0009571107,0.0001292394,0.003759293,0.00003563382,0.799176,0.002641379,0.1818523,0.001616233],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9773742,0.001574036,0.0003761242,0.001160724,0.0002027637,0.0002601692,0.0001861582,0.0002180628,0.0186478],"genre_scores_gemma":[0.9813397,0.0006446855,0.003583539,0.0001027129,0.0003475944,0.00002701138,0.0001914165,0.0001369708,0.01362637],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1819311,"threshold_uncertainty_score":0.9996132,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01503743269329132,"score_gpt":0.2182955060101061,"score_spread":0.2032580733168148,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}