{"id":"W2063846924","doi":"10.1002/jcc.20451","title":"Metal–thiolate bonds in bioinorganic chemistry","year":2006,"lang":"en","type":"review","venue":"Journal of Computational Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":132,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Institute of General Medical Sciences; Natural Sciences and Engineering Research Council of Canada","keywords":"Ionic bonding; Chemistry; Covalent bond; Crystallography; Chemical bond; Bioinorganic chemistry; Metal; Pi bond; Ligand (biochemistry); Hydrogen bond; Electron transfer; Redox; Molecular orbital; Bond order; Inorganic chemistry; Computational chemistry; Ion; Bond length; Photochemistry; Molecule; Stereochemistry; Crystal structure; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0006878948,0.0005102808,0.0004560226,0.0006610129,0.0004538032,0.0008846632,0.0007959874,0.00110781,0.007247625],"category_scores_gemma":[0.0004063337,0.0003740754,0.0002000463,0.0009280143,0.0007763981,0.001213943,0.0009860303,0.001273456,0.003886274],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001256018,"about_ca_system_score_gemma":0.0004607268,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003727407,"about_ca_topic_score_gemma":0.0005330165,"domain_scores_codex":[0.999534,0.00008258419,0.00003232779,0.00008766788,0.0002028296,0.00006067309],"domain_scores_gemma":[0.9998869,0.00003047023,0.00001656334,0.0000146889,0.00003235744,0.00001912586],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0001190028,0.0002944663,0.0004821146,0.003614698,0.00006774644,0.0005120565,0.0003466615,0.003417657,0.1653374,0.343894,0.03536265,0.4465515],"study_design_scores_gemma":[0.000039575,0.0004203945,0.0008272823,0.0002413589,0.00001972893,0.0006704982,0.00008404259,0.002754238,0.09771296,0.06695174,0.8302357,0.00004255105],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.05027803,0.6880542,0.05245565,0.007234109,0.006839802,0.0001673331,0.0003062539,0.0008362058,0.1938284],"genre_scores_gemma":[0.5182278,0.3196439,0.05257161,0.002689848,0.002561692,0.0003939371,0.0009114429,0.000193458,0.1028065],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.007247625,"threshold_uncertainty_score":0.02424574,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05607848127618029,"score_gpt":0.3222527947573917,"score_spread":0.2661743134812114,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}