{"id":"W2063846924","doi":"10.1002/jcc.20451","title":"Metal–thiolate bonds in bioinorganic chemistry","year":2006,"lang":"en","type":"review","venue":"Journal of Computational Chemistry","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":132,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Institute of General Medical Sciences; Natural Sciences and Engineering Research Council of Canada","keywords":"Ionic bonding; Chemistry; Covalent bond; Crystallography; Chemical bond; Bioinorganic chemistry; Metal; Pi bond; Ligand (biochemistry); Hydrogen bond; Electron transfer; Redox; Molecular orbital; Bond order; Inorganic chemistry; Computational chemistry; Ion; Bond length; Photochemistry; Molecule; Stereochemistry; Crystal structure; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0005075155,0.0004139307,0.002274788,0.000120815,0.00003598957,0.00003712188,0.00028526,0.0003380396,0.0005692025],"category_scores_gemma":[0.0001735335,0.000304144,0.0008103096,0.0003280195,0.00007023829,0.00007261529,0.00006149619,0.0009899543,0.00002298424],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002573579,"about_ca_system_score_gemma":0.001106669,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000025759,"about_ca_topic_score_gemma":1.17778e-7,"domain_scores_codex":[0.9970967,0.00006226127,0.001726028,0.0002453751,0.0006365097,0.0002331576],"domain_scores_gemma":[0.997828,0.000248331,0.00126644,0.000207601,0.0002988303,0.0001508017],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0004250344,0.001922323,0.0001045117,0.2427038,0.003655076,0.001882993,0.0000890113,0.002402366,0.02047078,0.00002230828,0.0117588,0.714563],"study_design_scores_gemma":[0.0006669917,0.00005810701,0.00003545313,0.01464293,0.001250436,0.005777745,0.000008847685,0.00005886021,0.001728448,0.0008384337,0.9745426,0.0003911953],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.002528385,0.9905799,0.00002611085,0.0000668201,0.0000620763,0.0001199967,0.00002010503,0.0000125045,0.006584127],"genre_scores_gemma":[0.00176483,0.9915307,0.001615656,0.00004912034,0.001080439,0.000007020181,0.0001946587,0.0000856493,0.003671957],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9627838,"threshold_uncertainty_score":0.9999411,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05607848127618029,"score_gpt":0.3222527947573917,"score_spread":0.2661743134812114,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}