{"id":"W2063887072","doi":"10.1021/ma991753c","title":"Rate Constants for the Trapping of Various Carbon-Centered Radicals by Nitroxides:  Unimolecular Initiators for Living Free Radical Polymerization","year":2000,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Polymer Synthesis and Characterization","field":"Chemistry","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"Xerox (Canada); University of Ottawa","funders":"","keywords":"Chemistry; Radical; Flash photolysis; Nitroxide mediated radical polymerization; Reaction rate constant; Radical polymerization; Polymerization; Photochemistry; Kinetics; Cobalt-mediated radical polymerization; Polymer chemistry; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.001717022,0.0006400574,0.0005988129,0.0005610944,0.0002155888,0.0003179817,0.0006935371,0.0006433382,0.002762486],"category_scores_gemma":[0.003617771,0.0003275109,0.0002811953,0.0003467638,0.0002880056,0.001123236,0.0001826971,0.001206808,0.0006503183],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000908975,"about_ca_system_score_gemma":0.000506548,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005407633,"about_ca_topic_score_gemma":0.0007844599,"domain_scores_codex":[0.9996058,0.00007331874,0.0000283032,0.0001081607,0.0001162005,0.00006818421],"domain_scores_gemma":[0.9973826,0.001666452,0.000373349,0.0001668149,0.0002689735,0.0001418738],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003729269,0.0001264257,0.0004500925,0.0002129682,0.00002244384,0.00002801499,0.0001132896,0.001314498,0.9879135,0.0005071989,0.00008530343,0.00885325],"study_design_scores_gemma":[0.00001628225,0.0002803407,0.0005241666,0.000007437529,0.0000176011,0.00003808452,0.00001199149,0.003216289,0.9951249,0.0000829799,0.000663011,0.00001699171],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9668016,0.005002992,0.02606507,0.0001027513,0.00004655898,0.0002013251,0.0003370347,0.0002025652,0.001240065],"genre_scores_gemma":[0.9789149,0.002733861,0.01456344,0.00003144705,0.00001702129,0.0002651226,0.0004727192,0.00007706338,0.002924478],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002762486,"threshold_uncertainty_score":0.009241462,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01020523494279484,"score_gpt":0.229599805636881,"score_spread":0.2193945706940862,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}