{"id":"W2064103813","doi":"10.1021/jo102358d","title":"A Synthesis of Acetamidines","year":2011,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":70,"is_retracted":false,"has_abstract":true,"ca_institutions":"Queen's University","funders":"","keywords":"Chemistry; Amine gas treating; Dimethylacetamide; Condensation; Primary (astronomy); Solvent; Crystallization; Distillation; Organic chemistry; Product distribution; Polymer chemistry; Combinatorial chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003199095,0.00009245335,0.0001981141,0.000009933285,0.00002543121,0.000003144659,0.0003920851,0.00007930031,0.00101852],"category_scores_gemma":[0.0003767553,0.00005725426,0.0001837345,0.00008922238,0.00009377495,0.000002317939,0.00007507422,0.00008501809,0.000002133828],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000007752894,"about_ca_system_score_gemma":0.00004831753,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000003809487,"about_ca_topic_score_gemma":0.00000102611,"domain_scores_codex":[0.9993468,0.00002641899,0.0003219606,0.00007043797,0.0001323786,0.0001020299],"domain_scores_gemma":[0.9991778,0.00003991545,0.0003471591,0.0002550626,0.0001257941,0.00005427413],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007615212,0.00006533976,0.0006493942,0.00002277742,0.0001666656,0.00000133477,0.00004966625,5.48704e-7,0.9978597,9.208455e-7,0.0003787295,0.0007287962],"study_design_scores_gemma":[0.0001042335,0.00002687369,0.0002779116,0.00002579732,0.0001922344,0.0001014786,0.0002009881,0.000001469141,0.9983041,0.00006090382,0.0006371722,0.0000667877],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965497,0.0007784436,0.0001866779,0.00009210092,0.00001929068,0.00001393088,0.000002743186,0.000001678335,0.002355422],"genre_scores_gemma":[0.9988184,0.0004908253,0.0002439422,0.00002234341,0.0001694619,4.224053e-7,7.311181e-7,0.0000118131,0.0002420426],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002268706,"threshold_uncertainty_score":0.9998947,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01031191310676028,"score_gpt":0.2020816576895466,"score_spread":0.1917697445827864,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}