{"id":"W2064116918","doi":"10.3749/canmin.46.6.1623","title":"NEPTUNYL COMPOUNDS: POLYHEDRON GEOMETRIES, BOND-VALENCE PARAMETERS, AND STRUCTURAL HIERARCHY","year":2008,"lang":"en","type":"article","venue":"The Canadian Mineralogist","topic":"Radioactive element chemistry and processing","field":"Chemistry","cited_by":77,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Office of Science; U.S. Department of Energy","keywords":"Polyhedron; Valence (chemistry); Valence bond theory; Crystallography; Hierarchy; Bond; Chemistry; Materials science; Mathematics; Geometry; Molecule; Economics; Molecular orbital; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001199096,0.0002454156,0.0002088202,0.00007580828,0.001113131,0.0001296443,0.0003894489,0.0001166429,0.0003170096],"category_scores_gemma":[0.0001100483,0.0001961252,0.00005201558,0.0002448255,0.00104612,0.000170474,0.00003912032,0.0003863285,0.000007715194],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002965225,"about_ca_system_score_gemma":0.0003458378,"about_ca_topic_candidate":true,"about_ca_topic_consensus":true,"about_ca_topic_score_codex":0.1012772,"about_ca_topic_score_gemma":0.06233333,"domain_scores_codex":[0.9986479,0.00001757823,0.0002200501,0.0003416642,0.0002106343,0.0005621896],"domain_scores_gemma":[0.9989386,0.0001332496,0.0000968176,0.0003804209,0.00004836476,0.0004025763],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0004168474,0.00008099545,0.31941,0.001011951,0.0007148729,0.001581098,0.007046347,0.0002725362,0.449839,0.003428195,0.1897583,0.02643988],"study_design_scores_gemma":[0.005558233,0.0002464711,0.05244164,0.0004382911,0.0003537982,0.007719238,0.002692558,0.002530293,0.3964368,0.0090212,0.5175493,0.005012215],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9704769,0.00206351,0.000006030674,0.001857841,0.00007352055,0.00006248915,0.0001883262,0.00004554759,0.0252258],"genre_scores_gemma":[0.9940185,0.0000886549,0.0003695694,0.0006142287,0.0002029857,0.0000101242,0.0001449166,0.00002114896,0.004529847],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3277911,"threshold_uncertainty_score":0.9547766,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02964233647411892,"score_gpt":0.2348305574406324,"score_spread":0.2051882209665135,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}