{"id":"W2064438562","doi":"10.1007/s007750000202","title":"Buffer-anion-dependent Ca2+ leaching from horseradish peroxidase at low pH","year":2001,"lang":"en","type":"article","venue":"JBIC Journal of Biological Inorganic Chemistry","topic":"Enzyme-mediated dye degradation","field":"Agricultural and Biological Sciences","cited_by":11,"is_retracted":false,"has_abstract":false,"ca_institutions":"Concordia University","funders":"Natural Sciences and Engineering Research Council of Canada; Concordia University; AstraZeneca","keywords":"Chemistry; Horseradish peroxidase; Peroxidase; Heme; Histidine; Phosphate; Formate; Ferric; Solvent; Inorganic chemistry; Nuclear chemistry; Catalysis; Amino acid; Enzyme; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004166836,0.0002650681,0.0004019369,0.00001039215,0.0002121801,0.00007555241,0.0005885032,0.0003976973,0.005504722],"category_scores_gemma":[0.0004606675,0.0001032681,0.0002299534,0.0002486705,0.00009757178,0.0001676967,0.0001736151,0.0006434572,0.00008549242],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002517172,"about_ca_system_score_gemma":0.00002418796,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001056491,"about_ca_topic_score_gemma":0.00005535371,"domain_scores_codex":[0.9980482,0.0001218743,0.0006734632,0.0003608992,0.0004051959,0.0003904024],"domain_scores_gemma":[0.9985198,0.0003993854,0.0005174681,0.000106292,0.0001442342,0.0003127976],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009540364,0.00019774,0.02213509,0.000003705161,0.00003692802,0.0001213117,0.00005049556,0.000002967303,0.9726942,0.000003104066,0.0007865503,0.00387254],"study_design_scores_gemma":[0.00111368,0.0004827381,0.160795,0.0001239302,0.00007262298,0.0009223637,0.001072846,0.00004397126,0.8275946,0.0009668347,0.006121795,0.0006895826],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9973568,0.0008953353,0.00001206917,0.001018677,0.0002407957,0.00007405537,0.00005427876,0.00005389045,0.0002940923],"genre_scores_gemma":[0.9969248,0.000699143,0.00006394987,0.0002949786,0.001447279,0.000002132496,0.0001982381,0.000002682454,0.000366782],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1450995,"threshold_uncertainty_score":0.9954044,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0164492482075705,"score_gpt":0.2131964131104526,"score_spread":0.1967471649028821,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}