{"id":"W2064546561","doi":"10.1021/ic0206903","title":"Cationic Carbonyl Complexes of Rhodium(I) and Rhodium(III):  Syntheses, Vibrational Spectra, NMR Studies, and Molecular Structures of Tetrakis(carbonyl)rhodium(I) Heptachlorodialuminate and -gallate, [Rh(CO)<sub>4</sub>][Al<sub>2</sub>Cl<sub>7</sub>] and [Rh(CO)<sub>4</sub>][Ga<sub>2</sub>Cl<sub>7</sub>]","year":2003,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of British Columbia","funders":"","keywords":"Rhodium; Chemistry; Cationic polymerization; Stereochemistry; Medicinal chemistry; Polymer chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001644554,0.0003420623,0.0002746358,0.0001534419,0.0001383798,0.000258506,0.0005904512,0.0003757023,0.001127274],"category_scores_gemma":[0.0002819144,0.0001676412,0.0001638739,0.0002284368,0.0002564985,0.0003195087,0.0004544444,0.0003684126,0.0006001184],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004160328,"about_ca_system_score_gemma":0.0002521653,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005111139,"about_ca_topic_score_gemma":0.0007622231,"domain_scores_codex":[0.9998104,0.0000266235,0.00001049696,0.00003766146,0.00007638619,0.00003842313],"domain_scores_gemma":[0.9998446,0.00001215353,0.00005404445,0.00001554692,0.00003605232,0.00003776619],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006846818,0.00001467873,0.00007867063,0.00008071426,0.00000471599,0.0000352482,0.00002599639,0.0001029398,0.9973462,0.0002914668,0.00005736121,0.001893515],"study_design_scores_gemma":[0.00001741489,0.0001170864,0.0002392111,0.000003906721,0.000008859894,0.0002071392,0.0000162812,0.0003545161,0.9960048,0.00003364667,0.002991357,0.000005671532],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9757608,0.003381384,0.01368778,0.0001268079,0.00004467766,0.0001134052,0.0002003571,0.0002163581,0.006468448],"genre_scores_gemma":[0.9844239,0.001115149,0.009620939,0.00005912158,0.00001994823,0.00007380971,0.0003586704,0.00006908185,0.004259288],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001127274,"threshold_uncertainty_score":0.003771126,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01099916112691989,"score_gpt":0.2279156795574683,"score_spread":0.2169165184305484,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}