{"id":"W2064583569","doi":"10.1039/b506324h","title":"Application of solid phase microextraction in the determination of paralytic shellfish poisoning toxins","year":2005,"lang":"en","type":"article","venue":"The Analyst","topic":"Marine Toxins and Detection Methods","field":"Environmental Science","cited_by":14,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Research Council Canada; University Grants Committee","keywords":"Chromatography; Chemistry; Solid-phase microextraction; Detection limit; Aqueous solution; Extraction (chemistry); High-performance liquid chromatography; Desorption; Salting out; Solvent; Gas chromatography–mass spectrometry; Mass spectrometry; Adsorption","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002205897,0.0005771773,0.000447533,0.0003409965,0.0002808039,0.0003098979,0.0003274435,0.0005128232,0.0005143544],"category_scores_gemma":[0.0003340247,0.0002963004,0.0002478611,0.0003758074,0.0003524003,0.0002502414,0.0004557282,0.0004750725,0.0003861707],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003438301,"about_ca_system_score_gemma":0.0004628038,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001089565,"about_ca_topic_score_gemma":0.003187043,"domain_scores_codex":[0.9996438,0.00004529071,0.00001896096,0.00009359865,0.00017427,0.00002415901],"domain_scores_gemma":[0.9997429,0.0001087294,0.00003771987,0.00001799565,0.00007342425,0.00001930063],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002154918,0.000009337315,0.0003747399,0.00005384559,0.000005008496,0.00003392788,0.00001033038,0.00009039086,0.9933292,0.00002396042,0.00002214367,0.006025609],"study_design_scores_gemma":[0.000006882954,0.0002668413,0.002914686,0.000006558303,0.00002202606,0.0002645875,0.00002050947,0.001544369,0.9930686,0.00004858975,0.001829023,0.000007381261],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8370761,0.01203778,0.1456888,0.0003100955,0.0001625564,0.0002463256,0.0006397661,0.0006512986,0.003187306],"genre_scores_gemma":[0.860207,0.005680696,0.1284575,0.0001786967,0.0000433293,0.0001074535,0.0004188571,0.00004111572,0.00486534],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001089565,"threshold_uncertainty_score":0.002494693,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0149776370694662,"score_gpt":0.3405705950974293,"score_spread":0.3255929580279631,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}