{"id":"W2064632436","doi":"10.1002/cjce.20615","title":"High pressure physical solubility of carbon dioxide (CO<sub>2</sub>) in mixed polyethylene glycol dimethyl ethers (Genosorb 1753)","year":2011,"lang":"en","type":"article","venue":"The Canadian Journal of Chemical Engineering","topic":"Phase Equilibria and Thermodynamics","field":"Engineering","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Regina","funders":"Natural Sciences and Engineering Research Council of Canada; Natural Resources Canada; Clariant","keywords":"Enthalpy; Solubility; Chemistry; Gibbs free energy; Thermodynamics; Non-random two-liquid model; Polyethylene glycol; Enthalpy change of solution; Carbon dioxide; Physical chemistry; Activity coefficient; Organic chemistry; Aqueous solution; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":true,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003105092,0.0002369394,0.0004562277,0.0001738955,0.00001754765,0.00001110028,0.0004406012,0.0001548333,0.000008286339],"category_scores_gemma":[0.0001172198,0.000207014,0.0001635315,0.0002501363,0.0001011096,0.0001073872,0.00001885903,0.0006943503,0.000001005367],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002213555,"about_ca_system_score_gemma":0.0001679757,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001771967,"about_ca_topic_score_gemma":0.0005284443,"domain_scores_codex":[0.9987129,0.0000360284,0.000458071,0.000122848,0.0002087786,0.0004613788],"domain_scores_gemma":[0.9990559,0.000118765,0.00009398808,0.0002832486,0.00005359247,0.0003944642],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003068347,0.00002001496,0.0001745708,0.00006953947,0.0001445474,0.00003373456,0.0009110796,0.05389545,0.9441856,0.0001653001,0.000005793212,0.0003637499],"study_design_scores_gemma":[0.0004383694,0.00003344615,0.001400368,0.00008888811,0.00006354313,0.00002684911,0.00001328963,0.05529259,0.9417831,0.000635911,0.00001861612,0.0002049845],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9986372,0.0005065787,0.0001440884,0.00003110514,0.0003391513,0.000115523,0.0000212621,0.00003093403,0.0001741398],"genre_scores_gemma":[0.999612,0.000005987395,0.0001276611,0.000006915166,0.0001806151,0.000004397851,0.000001812952,0.0000594007,0.000001251371],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002402389,"threshold_uncertainty_score":0.8441786,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008828202727052743,"score_gpt":0.1818041116298554,"score_spread":0.1729759089028027,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}