{"id":"W2064666394","doi":"10.1016/j.microc.2003.10.007","title":"Determination of major and trace elements in biological materials by microwave induced plasma optical emission spectrometry (MIP-OES) following tetramethylammonium hydroxide (TMAH) solubilization","year":2004,"lang":"en","type":"article","venue":"Microchemical Journal","topic":"Analytical chemistry methods development","field":"Chemistry","cited_by":48,"is_retracted":false,"has_abstract":false,"ca_institutions":"","funders":"National Research Council Canada","keywords":"Tetramethylammonium hydroxide; Certified reference materials; Chemistry; Hydroxide; Detection limit; Chromatography; Inductively coupled plasma; Analytical Chemistry (journal); Inductively coupled plasma atomic emission spectroscopy; Standard addition; Mass spectrometry; Microwave oven; Microwave digestion; Microwave; Plasma; Inorganic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0007906832,0.0003491678,0.0005920775,0.0001305264,0.00008732702,0.00008289359,0.0003119253,0.0005634797,0.0002304787],"category_scores_gemma":[0.0009617854,0.0003168649,0.0001424879,0.0002696653,0.0001239545,0.0001431502,0.0001669992,0.0007131362,0.000003068939],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0006106218,"about_ca_system_score_gemma":0.0001090066,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000005604826,"about_ca_topic_score_gemma":7.460557e-7,"domain_scores_codex":[0.9971763,0.00006589849,0.00125584,0.0005158617,0.0004196007,0.0005665185],"domain_scores_gemma":[0.9988301,0.0002356533,0.000369357,0.0001777786,0.00007700882,0.0003100397],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001453109,0.0002796996,0.001786887,0.00009950688,0.00004323874,0.00005929515,0.00008925694,4.200383e-7,0.9945173,0.00001241679,0.000009913379,0.002956735],"study_design_scores_gemma":[0.002248151,0.00005185138,0.0001944939,0.0003011855,0.00004811204,0.0002846037,0.0001786202,0.00003537298,0.9944817,0.001800052,0.00003630387,0.0003395668],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9835351,0.0002064034,0.01571958,0.0001674458,0.00005935229,0.00009338319,0.00001176829,0.00002533013,0.0001816811],"genre_scores_gemma":[0.8620508,0.00007393269,0.1376615,0.00002497606,0.00007672083,0.000006053702,0.00004470829,0.00002908369,0.00003229795],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1219419,"threshold_uncertainty_score":0.9999284,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01648983945271215,"score_gpt":0.2754830173643074,"score_spread":0.2589931779115953,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}