{"id":"W2064669884","doi":"10.1139/v08-016","title":"Wallach rearrangement of azoxypyridines and azoxypyridine <i>N</i>-oxides — Charge distributions and dramatic reactivity differences","year":2008,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Reactivity (psychology); Protonation; Charge (physics); Computational chemistry; Medicinal chemistry; Molecule; Stereochemistry; Organic chemistry; Ion","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001513345,0.0001994683,0.000414922,0.00005126707,0.0001486086,0.00002925061,0.0001855391,0.000149235,0.0006878273],"category_scores_gemma":[0.0004890066,0.0001854105,0.00009327482,0.0001105281,0.0003056352,0.0001380199,0.0000285836,0.0003329166,0.00000105713],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001479399,"about_ca_system_score_gemma":0.0004062292,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006320556,"about_ca_topic_score_gemma":0.0001544549,"domain_scores_codex":[0.9988002,0.00001000183,0.0004722328,0.0001903876,0.0002437173,0.0002835075],"domain_scores_gemma":[0.9983252,0.0001428237,0.0004044004,0.0002078553,0.00020071,0.000718958],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001881528,0.00003661818,0.008810035,0.0002805165,0.00005792865,0.0000751408,0.0002124737,2.009309e-7,0.9894238,0.00002347098,0.0005370651,0.0005239235],"study_design_scores_gemma":[0.0005129517,0.00001982931,0.002279997,0.0002180418,0.00005404792,0.001143995,0.0002067132,0.00002857305,0.9928874,0.0004083202,0.002055487,0.0001846476],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9959181,0.001125504,0.00003372845,0.0004861651,0.00004660905,0.00003200674,0.0001222088,0.000009580271,0.002226103],"genre_scores_gemma":[0.9988526,0.0004078205,0.0001418126,0.00001634528,0.0001348737,0.000003327906,0.0000157363,0.00001558655,0.0004119127],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006530038,"threshold_uncertainty_score":0.7560821,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01742614021606441,"score_gpt":0.2056557600280363,"score_spread":0.1882296198119719,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}