{"id":"W2064959890","doi":"10.1002/ejic.200500818","title":"Palladium(<scp>II</scp>) Compounds with Fluorinated Pincer‐Type (SCS) Ligands: X‐ray Structures of C<sub>6</sub>H<sub>4</sub>‐1,3‐(CH<sub>2</sub>SC<sub>6</sub>H<sub>4</sub>F‐4)<sub>2</sub> and [PdCl(SCS–R<sub>f</sub>)] [R<sub>f</sub> = C<sub>6</sub>H<sub>4</sub>F‐2, C<sub>6</sub>H<sub>4</sub>F‐3, C<sub>6</sub>H<sub>4</sub>F‐4, C<sub>6</sub>H<sub>4</sub>(CF<sub>3</sub>)‐2, and C<sub>6</sub>H<sub>4</sub>(CF<sub>3</sub>)‐4]","year":2006,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Consejo Nacional de Ciencia y Tecnología","keywords":"Chemistry; Pincer movement; Palladium; Metathesis; Stereochemistry; Crystallography; Medicinal chemistry; X-ray crystallography; X-ray; Catalysis; Diffraction; Polymerization; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity","insufficient_payload"],"consensus_categories":["metaresearch","metaepi_narrow","metaepi_broad","bibliometrics","sts","scholarly_communication","open_science","research_integrity"],"category_scores_codex":[0.02958904,0.04929768,0.04456269,0.02114246,0.02127908,0.01789797,0.03582842,0.02543733,0.0005662409],"category_scores_gemma":[0.01626268,0.05537464,0.02616465,0.04129617,0.02415386,0.02097981,0.02441831,0.04921319,0.01028084],"about_ca_system_candidate":true,"about_ca_system_consensus":true,"about_ca_system_score_codex":0.02470333,"about_ca_system_score_gemma":0.02170734,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004928156,"about_ca_topic_score_gemma":0.00531526,"domain_scores_codex":[0.827105,0.01515553,0.04537813,0.0391365,0.0331396,0.04008519],"domain_scores_gemma":[0.8605043,0.0146735,0.04313582,0.03247946,0.02029182,0.02891508],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0147975,0.01656072,0.003733551,0.01266879,0.0224514,0.01561042,0.006185992,0.003976422,0.7740142,0.0004138032,0.03875346,0.09083373],"study_design_scores_gemma":[0.04646553,0.007541361,0.01195107,0.01506938,0.02356145,0.01995835,0.006760009,0.00248462,0.8158075,0.002831955,0.006308009,0.04126076],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9002667,0.02640064,0.002557707,0.003269151,0.01523054,0.01974281,0.0163339,0.01242524,0.003773307],"genre_scores_gemma":[0.8542726,0.07374276,0.0009519322,0.005239952,0.02411953,0.004412704,0.0182786,0.01879091,0.0001910194],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04957298,"threshold_uncertainty_score":0.9992423,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007241840515502268,"score_gpt":0.1863779061026713,"score_spread":0.179136065587169,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}