{"id":"W2064959890","doi":"10.1002/ejic.200500818","title":"Palladium(<scp>II</scp>) Compounds with Fluorinated Pincer‐Type (SCS) Ligands: X‐ray Structures of C<sub>6</sub>H<sub>4</sub>‐1,3‐(CH<sub>2</sub>SC<sub>6</sub>H<sub>4</sub>F‐4)<sub>2</sub> and [PdCl(SCS–R<sub>f</sub>)] [R<sub>f</sub> = C<sub>6</sub>H<sub>4</sub>F‐2, C<sub>6</sub>H<sub>4</sub>F‐3, C<sub>6</sub>H<sub>4</sub>F‐4, C<sub>6</sub>H<sub>4</sub>(CF<sub>3</sub>)‐2, and C<sub>6</sub>H<sub>4</sub>(CF<sub>3</sub>)‐4]","year":2006,"lang":"en","type":"article","venue":"European Journal of Inorganic Chemistry","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":15,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Windsor","funders":"Consejo Nacional de Ciencia y Tecnología","keywords":"Chemistry; Pincer movement; Palladium; Metathesis; Stereochemistry; Crystallography; Medicinal chemistry; X-ray crystallography; X-ray; Catalysis; Diffraction; Polymerization; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00005876534,0.0004218479,0.000179738,0.0001771403,0.0001763023,0.0003582054,0.000330715,0.000227049,0.003003495],"category_scores_gemma":[0.000143892,0.000195903,0.000106703,0.0002659827,0.0002208056,0.0001991186,0.0003079688,0.0002764419,0.0004179034],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005287948,"about_ca_system_score_gemma":0.0001670548,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001717699,"about_ca_topic_score_gemma":0.001569383,"domain_scores_codex":[0.9999399,0.000008356023,0.000002655515,0.00001134743,0.00001507703,0.0000227737],"domain_scores_gemma":[0.9999667,0.000005177697,0.00001177704,0.000004521019,0.000004617589,0.000007126276],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006847534,0.00002234679,0.0003548476,0.0001985023,0.0000312326,0.0002059365,0.00008397265,0.00121974,0.9901799,0.001070556,0.0007196288,0.005228582],"study_design_scores_gemma":[0.00002830764,0.0001953509,0.0008832664,0.000005548749,0.00001468922,0.0001664957,0.00002941888,0.0003721893,0.9943153,0.00007467053,0.003908438,0.00000616445],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9826747,0.0009271069,0.002637125,0.00008882738,0.00002234917,0.00003429699,0.000376553,0.0003926105,0.0128465],"genre_scores_gemma":[0.9929019,0.000388358,0.001373254,0.00003691514,0.000003528413,0.000024026,0.0004418263,0.00004023356,0.004789921],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003003495,"threshold_uncertainty_score":0.01004773,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007241840515502268,"score_gpt":0.1863779061026713,"score_spread":0.179136065587169,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}