{"id":"W2065000688","doi":"10.1021/ic049759s","title":"Syntheses and Characterization of the MF<sub>6</sub><sup>-</sup>(M = As, Sb) Salts of the Simple Trithietanylium PhCS<sub>3</sub><sup>+</sup>Cation and the Identity of PhCS<sub>3</sub>Cl","year":2005,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"","keywords":"Chemistry; Raman spectroscopy; Spectroscopy; Infrared spectroscopy; Crystallography; Nuclear magnetic resonance spectroscopy; Analytical Chemistry (journal); Physical chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0008117533,0.000761717,0.001009064,0.00007510262,0.0005716566,0.0001513163,0.00133612,0.000887523,0.0001570878],"category_scores_gemma":[0.0008930677,0.0005360612,0.000452206,0.000906121,0.001246195,0.0005036494,0.0008343739,0.001165851,0.00001574459],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002752108,"about_ca_system_score_gemma":0.0004614108,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007705922,"about_ca_topic_score_gemma":0.00002216566,"domain_scores_codex":[0.995406,0.000196737,0.00167859,0.0009007308,0.001115065,0.0007028785],"domain_scores_gemma":[0.9953786,0.0006113247,0.001511395,0.001796997,0.0005055862,0.0001961232],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002270253,0.0003027701,0.001558071,0.001001377,0.0003614672,0.000002675833,0.001706588,0.0001157985,0.9912404,0.0001229796,0.0001900977,0.003170706],"study_design_scores_gemma":[0.002154642,0.00002774197,0.001652125,0.0005710343,0.0005486001,0.0002079749,0.0008532806,0.002349736,0.9903015,0.000533533,0.0002627318,0.0005370505],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9958814,0.00111487,0.000033363,0.001025002,0.0001402026,0.0005052203,0.0002707029,0.0001019275,0.0009273581],"genre_scores_gemma":[0.9968835,0.0019802,0.00001116128,0.0001564075,0.0005734015,0.00003813244,0.000110125,0.0001350428,0.0001120493],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002633655,"threshold_uncertainty_score":0.9997091,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005181931994932695,"score_gpt":0.1925995225310377,"score_spread":0.187417590536105,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}