{"id":"W2065036974","doi":"10.1002/chin.200319098","title":"Electron‐Deficient Dienes. Part 3. Rapid Access to 2‐Hydroxybenzophenones via Inverse Electron Demand Diels—Alder‐Driven Domino Reactions of a Chromone‐Fused Electron‐Deficient Diene with Enamines.","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Synthesis of Organic Compounds","field":"Medicine","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Chemistry; Domino; Chromone; Diene; Electron; Medicinal chemistry; Photochemistry; Organic chemistry; Catalysis; Physics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001980423,0.0006316412,0.0002296118,0.0002941523,0.0001814756,0.00018687,0.000378331,0.0002863966,0.00541153],"category_scores_gemma":[0.0001430225,0.000195214,0.0002531535,0.0001605057,0.0002651132,0.0004460987,0.0002969931,0.0003853516,0.001100408],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000247637,"about_ca_system_score_gemma":0.0002456808,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002601396,"about_ca_topic_score_gemma":0.0007143275,"domain_scores_codex":[0.9999216,0.00001390548,0.000006355745,0.00001436438,0.00001961005,0.00002418024],"domain_scores_gemma":[0.9999677,0.000009553115,0.000006023798,0.000006284366,0.00000391259,0.000006438171],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00032215,0.00007800465,0.0001060805,0.0006518089,0.00002275141,0.000317829,0.00008355121,0.001062319,0.9546055,0.00545996,0.002583231,0.03470679],"study_design_scores_gemma":[0.00003865621,0.0003835935,0.0006911967,0.00002475746,0.00001820011,0.0003876024,0.00001719523,0.0004505602,0.9650015,0.000947464,0.03202501,0.0000143531],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7052323,0.04682346,0.1337296,0.001347155,0.001759993,0.0006442539,0.005174934,0.001530697,0.1037576],"genre_scores_gemma":[0.9095153,0.01728756,0.02271705,0.0004377987,0.0001245664,0.0002947414,0.002423733,0.00008651244,0.04711263],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00541153,"threshold_uncertainty_score":0.01810336,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01494615702171504,"score_gpt":0.2523775286062789,"score_spread":0.2374313715845638,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}