{"id":"W2065378639","doi":"10.1016/j.jcou.2014.04.001","title":"A thermodynamic resolution of dimethyl carbonate decarboxylation and the first example of its reversibility: Dimethyl ether carboxylation","year":2014,"lang":"en","type":"article","venue":"Journal of CO2 Utilization","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":7,"is_retracted":false,"has_abstract":false,"ca_institutions":"Université de Sherbrooke","funders":"Alberta Innovates; Compute Canada; Climate Change and Emissions Management Corporation; Enerkem","keywords":"Carboxylation; Dimethyl carbonate; Decarboxylation; Dimethyl ether; Chemistry; Catalysis; Organic chemistry; Inorganic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.002042447,0.0001724861,0.0004987477,0.0002947862,0.00005381567,0.00001582648,0.0001987565,0.0001671725,0.00002784578],"category_scores_gemma":[0.001754678,0.0001355755,0.0001899655,0.0006685859,0.0001680227,0.0002660627,0.00006024176,0.0001990458,5.888937e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001168756,"about_ca_system_score_gemma":0.00004648497,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001528354,"about_ca_topic_score_gemma":0.00005177301,"domain_scores_codex":[0.9977211,0.0002596914,0.001091078,0.000192572,0.0005887384,0.0001467981],"domain_scores_gemma":[0.9966611,0.0008365512,0.001290547,0.0003515299,0.0008018583,0.00005842796],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.002684305,0.0003065528,0.02520049,0.001367278,0.0008996802,0.000001546282,0.008729329,0.3375409,0.5242305,0.08667281,0.00008575232,0.01228088],"study_design_scores_gemma":[0.002353854,0.00008014216,0.0120609,0.000188912,0.0003458078,0.00000824244,0.0001267461,0.9321306,0.04922874,0.0028801,0.000441043,0.0001549419],"study_design_candidate":"simulation_or_modeling","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8826197,0.001675742,0.1137134,0.0002280718,0.000218378,0.0003051465,0.000007255238,0.00002484067,0.001207365],"genre_scores_gemma":[0.9990184,0.0002390205,0.0005546657,0.00002663651,0.00007566746,0.000004305983,0.00001387406,0.00002960815,0.00003777421],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.5945897,"threshold_uncertainty_score":0.5528609,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02095571552020947,"score_gpt":0.244581271270233,"score_spread":0.2236255557500235,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}