{"id":"W2065461984","doi":"10.1021/om0702330","title":"Reactivity of (C<sub>5</sub>Me<sub>5</sub>)Lu(CH<sub>2</sub>SiMe<sub>3</sub>)<sub>2</sub>(THF) with Pyridine Ring Systems:  Synthesis and Structural Characterization of an η<sup>2</sup>-(N,C)-Pyridyl (Mono)pentamethylcyclopentadienyl Lutetium(III) Complex","year":2007,"lang":"en","type":"article","venue":"Organometallics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":44,"is_retracted":false,"has_abstract":true,"ca_institutions":"Simon Fraser University","funders":"","keywords":"Chemistry; Reactivity (psychology); Pyridine; Metallacycle; Metalation; Crystallography; Ligand (biochemistry); Ring (chemistry); Lanthanide; Stereochemistry; Metathesis; Bond length; Square pyramid; X-ray crystallography; Crystal structure; Agostic interaction; Metal; Medicinal chemistry; Ion; Diffraction; Polymerization","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001158946,0.0001770943,0.0001323456,0.00007600283,0.0001356652,0.0002777994,0.0002576237,0.0002086446,0.000995854],"category_scores_gemma":[0.0003342783,0.0001033543,0.00008365464,0.00009555888,0.0002002027,0.0001770513,0.0001814221,0.0001339315,0.0001872256],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005000741,"about_ca_system_score_gemma":0.0001516394,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001422829,"about_ca_topic_score_gemma":0.002110594,"domain_scores_codex":[0.9998902,0.00002328678,0.000006020586,0.00002024588,0.00003268512,0.00002749131],"domain_scores_gemma":[0.9999361,0.00001615097,0.00001950097,0.00001060489,0.000007124617,0.000010469],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001459136,0.000007917173,0.000366507,0.00004435378,0.000007266025,0.00008162687,0.00004882206,0.0003278717,0.997435,0.0002163562,0.00004073603,0.001277581],"study_design_scores_gemma":[0.000004628417,0.00007242603,0.0005836122,0.000001218316,0.000004059066,0.00008997926,0.00001277423,0.000503951,0.9981526,0.00001684893,0.0005555165,0.000002399959],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9974733,0.0003699335,0.0006761897,0.0000180999,0.000003428956,0.000006220565,0.00005152809,0.0000216897,0.001379612],"genre_scores_gemma":[0.9984404,0.00009678369,0.0004820964,0.000006207813,9.87986e-7,0.000003423977,0.00006826704,0.000004770178,0.0008971184],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001422829,"threshold_uncertainty_score":0.003628254,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01212076280358821,"score_gpt":0.212696679928619,"score_spread":0.2005759171250308,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}