{"id":"W2065630525","doi":"10.1002/ejoc.201000359","title":"Pd‐PEPPSI Complexes and the Negishi Reaction","year":2010,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":221,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"","keywords":"Negishi coupling; Chemistry; Steric effects; Combinatorial chemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002101252,0.0005705041,0.0002674798,0.0001820315,0.000209151,0.0005059091,0.0004969304,0.0004080678,0.002669478],"category_scores_gemma":[0.0001968874,0.0003454466,0.0001898157,0.0001794417,0.0002782028,0.0006645271,0.0004928295,0.0007454206,0.0007202928],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003243669,"about_ca_system_score_gemma":0.0001488379,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003401771,"about_ca_topic_score_gemma":0.0004365054,"domain_scores_codex":[0.9999164,0.00001380221,0.000005446317,0.00001729038,0.00002997524,0.00001710002],"domain_scores_gemma":[0.9999664,0.00001322341,0.000007761581,0.00000416305,0.000004184641,0.000004276529],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0006051321,0.000147014,0.000742346,0.003568004,0.0001729108,0.001702508,0.0003651612,0.02204342,0.7765085,0.1136344,0.002898198,0.07761242],"study_design_scores_gemma":[0.00006765313,0.0007535417,0.0007346371,0.0001002132,0.0001026507,0.001423716,0.00007904256,0.01011676,0.8599028,0.009278477,0.1173949,0.00004561015],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7190157,0.06734151,0.06881342,0.0009005656,0.0003199197,0.0002342604,0.0004213259,0.0004213986,0.142532],"genre_scores_gemma":[0.9583689,0.02260233,0.007010365,0.0001495901,0.0000488651,0.0000757866,0.0002406296,0.00003373476,0.01146973],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002669478,"threshold_uncertainty_score":0.008930326,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007597910300986443,"score_gpt":0.2185216339038079,"score_spread":0.2109237236028215,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}