{"id":"W2065718858","doi":"10.1139/v00-167","title":"The photochemistry of the 4-cyanobenzoic acid esters of <i>trans</i>- and <i>cis</i>-2-phenylcyclohexanol","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":1,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Dalhousie University","keywords":"Chemistry; Intramolecular force; Photochemistry; Flash photolysis; Isomerization; Photodissociation; Electron transfer; Radical ion; Exergonic reaction; Singlet state; Methanol; Excited state; Stereochemistry; Ion; Catalysis; Reaction rate constant; Organic chemistry; Kinetics","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002407931,0.0002877952,0.0004385021,0.00002045187,0.0003122815,0.0000386532,0.000957348,0.0002091459,0.0002425826],"category_scores_gemma":[0.0001660362,0.0002011041,0.0003161275,0.0002222848,0.0008917456,0.00007889019,0.00003159112,0.0006187593,1.764338e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001021952,"about_ca_system_score_gemma":0.001016507,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002667442,"about_ca_topic_score_gemma":0.0004528301,"domain_scores_codex":[0.9981564,0.000016502,0.0007692424,0.0002036012,0.0003461809,0.0005080996],"domain_scores_gemma":[0.9981703,0.0001425601,0.000472128,0.0005322775,0.0002706221,0.0004120724],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001017501,0.00002380762,0.004641114,0.0004020403,0.0001994204,0.00002812878,0.000383581,0.000005226001,0.9928916,0.000003169542,0.0007171422,0.0006030104],"study_design_scores_gemma":[0.0007412974,0.00001812781,0.0001930224,0.0002688991,0.0001209564,0.0006083315,0.0007529649,0.000002771119,0.9780931,0.0001516125,0.01886359,0.000185324],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9749579,0.006535377,0.00002305938,0.0006125225,0.00008817782,0.00006636362,0.00007256275,0.000006355695,0.01763762],"genre_scores_gemma":[0.9984109,0.0005351735,0.00001720294,0.0000611933,0.0001449531,0.0000083838,0.000002778131,0.00002569115,0.0007936941],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02345297,"threshold_uncertainty_score":0.8200788,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005649003224075566,"score_gpt":0.1868153822612207,"score_spread":0.1811663790371451,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}