{"id":"W2065768491","doi":"10.1021/la0608718","title":"Titrametric Characterization of pH-Induced Phase Transitions in Functionalized Microgels","year":2006,"lang":"en","type":"article","venue":"Langmuir","topic":"Hydrogels: synthesis, properties, applications","field":"Biochemistry, Genetics and Molecular Biology","cited_by":111,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Potentiometric titration; Monomer; Chemistry; Gibbs free energy; Isothermal titration calorimetry; Titration; Polymer chemistry; Enthalpy; Physical chemistry; Carboxylic acid; Polymer; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007608673,0.00008470217,0.0001146508,0.0001113292,0.00003640655,0.000007581279,0.00008239383,0.00009755095,0.00008314011],"category_scores_gemma":[0.00001333219,0.00008517065,0.00005802124,0.0002712933,0.00003098403,0.000004860838,0.00001162436,0.00004139885,0.00001603457],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001386055,"about_ca_system_score_gemma":0.00003275294,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001107345,"about_ca_topic_score_gemma":0.0000566456,"domain_scores_codex":[0.9993681,0.00003764706,0.0002184698,0.0001812151,0.00007525305,0.0001192772],"domain_scores_gemma":[0.9996907,0.00000441513,0.00006518823,0.0001712283,0.00004871285,0.00001975614],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000333368,0.0002822999,0.0004047292,0.00001194179,0.00001214415,4.901389e-7,0.00002934328,0.000004742062,0.9963918,0.0002030574,0.00006971221,0.002556388],"study_design_scores_gemma":[0.0009461753,0.00005609974,0.01966718,0.000007757725,0.00001736416,0.000005409084,0.00001652966,0.00008438984,0.9542384,0.00004965937,0.02478945,0.0001216232],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9965981,0.0001512171,0.001716625,0.0002568645,0.00002565492,0.0001939054,0.000114631,0.00001475746,0.0009282878],"genre_scores_gemma":[0.9981161,0.00001237136,0.0002032424,0.00008251965,0.0001014893,0.00008223748,0.0009705797,0.00001603846,0.0004153621],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.04215345,"threshold_uncertainty_score":0.3473158,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01598647203964546,"score_gpt":0.2470881383264746,"score_spread":0.2311016662868292,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}