{"id":"W2065800166","doi":"10.1021/jo2025652","title":"Palladium-Catalyzed Ullmann-Type Reductive Homocoupling of Iodoaryl Glycosides","year":2012,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Carbohydrate Chemistry and Synthesis","field":"Chemistry","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université du Québec à Montréal","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Palladium; Divalent; Catalysis; Glycoside; Chemistry; Combinatorial chemistry; Coupling reaction; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001991795,0.000545148,0.0002987219,0.0002713675,0.0001915569,0.0003105717,0.0004770183,0.0002424098,0.0007429085],"category_scores_gemma":[0.0001695889,0.0001942078,0.0001826536,0.0003373152,0.0001613321,0.0002736413,0.0004196053,0.0005952862,0.0005958885],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003238753,"about_ca_system_score_gemma":0.000254216,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000430624,"about_ca_topic_score_gemma":0.001099326,"domain_scores_codex":[0.9998323,0.00002000091,0.00001666072,0.00004231763,0.00004347214,0.00004523548],"domain_scores_gemma":[0.9999388,0.000006594329,0.00001362755,0.00001245034,0.00001130397,0.00001716282],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003544028,0.00002619163,0.00009234228,0.00008013164,0.000008589153,0.0001001568,0.0000306773,0.0002196299,0.9908697,0.0005756798,0.0000900385,0.007871368],"study_design_scores_gemma":[0.000004080588,0.00004889442,0.0002301288,0.000002492972,0.000008278331,0.00009737207,0.000005255067,0.0003337821,0.9976833,0.00004843769,0.001534382,0.000003593209],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9187711,0.003460585,0.06032186,0.0002064047,0.00006730082,0.0001133125,0.0005286768,0.0005050368,0.01602587],"genre_scores_gemma":[0.9733642,0.001976915,0.01934169,0.0000740923,0.00001352457,0.00004284397,0.0004329415,0.00006580284,0.004688012],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007429085,"threshold_uncertainty_score":0.002485275,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01614354999863101,"score_gpt":0.2301085001143165,"score_spread":0.2139649501156855,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}