{"id":"W2065931327","doi":"10.1021/jp014644k","title":"Photoinduced Processes in Heterogeneous Gas−Solid Systems. Temperature Dependence (100−600 K) and Modeling of a Surface Chemical Reaction on Zirconia that Triggers Photophysical Events in the Solid","year":2002,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Catalysis and Oxidation Reactions","field":"Chemical Engineering","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"Concordia University","funders":"","keywords":"Activation energy; Hydrogen; Chemistry; Methane; Molecule; Photochemistry; Physical chemistry; Chemical reaction; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002380179,0.0001877381,0.0003982077,0.00003250213,0.0000406115,0.00001968903,0.0002893177,0.0001023504,0.000006672563],"category_scores_gemma":[0.0001486264,0.0001177711,0.0001202788,0.0003160464,0.00004323608,0.0001441244,0.00002751927,0.000759597,0.000001768481],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001004852,"about_ca_system_score_gemma":0.00002821751,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000405565,"about_ca_topic_score_gemma":0.000002036414,"domain_scores_codex":[0.9987064,0.0000490733,0.0004244384,0.0001624122,0.0004616323,0.000196025],"domain_scores_gemma":[0.9990176,0.0003272389,0.0002656152,0.0002211745,0.000100686,0.0000676997],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008412954,0.000332544,0.00001249684,0.000115187,0.00003181519,0.000006385674,0.0007437236,0.08352528,0.9151103,0.000001720902,0.00000521024,0.00003115493],"study_design_scores_gemma":[0.0004573587,0.00002929043,0.00001260744,0.0002527121,0.00004696696,0.0001227202,0.0003989853,0.1867893,0.8117577,0.00002549229,0.000004436119,0.0001023825],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9994556,0.0001536038,0.00002361889,0.0001194382,0.00002068334,0.0001176158,0.000005963983,0.000007962361,0.00009550364],"genre_scores_gemma":[0.9996861,0.00009578387,0.000005425614,0.00001529886,0.0001512552,0.000006765236,0.000003444096,0.00001546167,0.00002041924],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1033526,"threshold_uncertainty_score":0.4802564,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.022446235812921,"score_gpt":0.2557678663437409,"score_spread":0.2333216305308199,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}