{"id":"W2065980454","doi":"10.1016/s1044-0305(01)00297-5","title":"Formation of molecular radical cations of enkephalin derivatives via collision-induced dissociation of electrospray-generated copper (II) complex ions of amines and peptides","year":2001,"lang":"en","type":"article","venue":"Journal of the American Society for Mass Spectrometry","topic":"Mass Spectrometry Techniques and Applications","field":"Chemistry","cited_by":100,"is_retracted":false,"has_abstract":true,"ca_institutions":"York University","funders":"Hospital for Sick Children; York University","keywords":"Chemistry; Fragmentation (computing); Ion; Dissociation (chemistry); Protonation; Peptide; Collision-induced dissociation; Amine gas treating; Residue (chemistry); Electrospray; Mass spectrometry; Stereochemistry; Medicinal chemistry; Tandem mass spectrometry; Organic chemistry; Chromatography; Biochemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003763658,0.0003365055,0.0002157358,0.0002819782,0.0002363829,0.000348746,0.0004288138,0.0003496642,0.00109914],"category_scores_gemma":[0.000614397,0.0002242577,0.0001800117,0.0001946447,0.0002831932,0.0003522853,0.0003227687,0.0005098568,0.000272083],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004134781,"about_ca_system_score_gemma":0.0002407904,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003124221,"about_ca_topic_score_gemma":0.0004655063,"domain_scores_codex":[0.9998047,0.00002541104,0.00001107689,0.00004549116,0.00006498764,0.00004840362],"domain_scores_gemma":[0.9997422,0.00005134799,0.00007536739,0.00002856191,0.00005139511,0.0000511679],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001643591,0.00002122042,0.0002204262,0.00004381419,0.00001192873,0.0001582274,0.00006428211,0.00009462258,0.9954853,0.0004326721,0.0001212316,0.003181858],"study_design_scores_gemma":[0.00003513517,0.0001150197,0.0005524771,0.000003071166,0.000006269314,0.0002396985,0.0000126328,0.0005584892,0.9972882,0.00007407978,0.001109016,0.000005828155],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9887753,0.0009131188,0.007911106,0.00009735968,0.00004076177,0.00006409156,0.00009107668,0.0001307483,0.001976466],"genre_scores_gemma":[0.9885079,0.0005343411,0.008039467,0.00007303202,0.00001689422,0.00003916989,0.0002463308,0.00004217773,0.002500613],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00109914,"threshold_uncertainty_score":0.003677011,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01603165376567833,"score_gpt":0.2810496167454092,"score_spread":0.2650179629797309,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}