{"id":"W2066211249","doi":"10.1139/v02-009","title":"Medium-sized cyclophanes, part 59:<sup>1</sup> Nitration of [3.3]- and [3.3.3]metacyclophanes Through-space electronic interactions between two or three benzene rings","year":2002,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Supramolecular Chemistry and Complexes","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Nitration; Chemistry; Acetic anhydride; Nitric acid; Medicinal chemistry; Electrophilic aromatic substitution; Reagent; Benzene; Electrophile; Acetic acid; Reactivity (psychology); Ring (chemistry); Organic chemistry; Catalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001882999,0.0003742515,0.0006243894,0.00007025301,0.0002051744,0.00009817777,0.00052093,0.0002162428,0.005300387],"category_scores_gemma":[0.0003486255,0.0003637225,0.000234423,0.0002666589,0.0002538467,0.00036356,0.00003574205,0.000781091,0.000005274744],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002393127,"about_ca_system_score_gemma":0.0008768369,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007357623,"about_ca_topic_score_gemma":0.00154755,"domain_scores_codex":[0.9978118,0.00002575194,0.0008447929,0.0003340288,0.0003595068,0.000624128],"domain_scores_gemma":[0.9978184,0.0002364388,0.0006208112,0.000425357,0.00026529,0.0006337403],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002278697,0.0001522842,0.01696366,0.001017718,0.001285057,0.0005601128,0.001888826,0.0002730604,0.9672002,0.00009175928,0.004564213,0.005775246],"study_design_scores_gemma":[0.001853661,0.00004813663,0.0001903527,0.0004025902,0.0002992656,0.001611094,0.0007696134,0.000209245,0.9521095,0.001134949,0.04089407,0.0004775173],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9869556,0.002960056,0.0001030349,0.0007898044,0.00005353343,0.00005429006,0.00007142396,0.00002324753,0.008989038],"genre_scores_gemma":[0.9966775,0.0002645903,0.0003088625,0.00005689994,0.0008968159,0.000008853554,0.00004547662,0.00004763702,0.001693387],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.03632986,"threshold_uncertainty_score":0.9998814,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02272270640499102,"score_gpt":0.2422438785718055,"score_spread":0.2195211721668145,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}