{"id":"W2066328456","doi":"10.1002/chin.200318276","title":"Alkyl Phosphines as Reagents and Catalysts in Organic Synthesis","year":2003,"lang":"en","type":"article","venue":"ChemInform","topic":"Phosphorus compounds and reactions","field":"Chemistry","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"Regional Municipality of Niagara","funders":"","keywords":"Chemistry; Reagent; Catalysis; Alkyl; Combinatorial chemistry; Organic synthesis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006695164,0.0001349483,0.0001560919,0.00003256718,0.00006751913,0.00002929933,0.0001020064,0.0001073601,0.001589862],"category_scores_gemma":[0.0002354051,0.0001209864,0.00003708031,0.0001393591,0.00004249736,0.0001455403,0.00003666918,0.0001278374,0.00007856829],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008411604,"about_ca_system_score_gemma":0.00005443253,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001471713,"about_ca_topic_score_gemma":0.00006370302,"domain_scores_codex":[0.9993272,1.874512e-7,0.0001897533,0.0001690701,0.0001052797,0.0002084525],"domain_scores_gemma":[0.9995139,0.00006933114,0.00005607746,0.0002460356,0.00002069173,0.0000940094],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009492576,0.0006805911,0.02731602,0.0006649493,0.0003168337,0.0001605736,0.003392189,4.339772e-7,0.6089464,0.002902959,0.02311774,0.3324064],"study_design_scores_gemma":[0.000214503,0.000002559702,0.0005252025,0.00004812319,0.00001560233,0.00007458027,0.0003315147,0.000002889022,0.9065169,0.0002377846,0.09187138,0.0001589425],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.4457011,0.0002795976,5.244529e-8,0.00003812627,0.00003645183,0.00002138332,0.000003200326,0.00003024767,0.5538898],"genre_scores_gemma":[0.9813714,0.0004171008,0.00001777517,0.00004508506,0.00002341974,0.00002250247,0.00001149229,0.0000161514,0.01807504],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.5358148,"threshold_uncertainty_score":0.9993228,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007942324239631942,"score_gpt":0.2161568467272017,"score_spread":0.2082145224875698,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}