{"id":"W2066477469","doi":"10.1021/ja051218u","title":"Molecular AND and INHIBIT Gates Based on Control of Porphyrin Fluorescence by Photochromes","year":2005,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":140,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Division of Chemistry","keywords":"Porphyrin; Chemistry; Triad (sociology); Photochemistry; Quenching (fluorescence); Fluorescence; Isomerization; Photoinduced electron transfer; Molecular switch; Covalent bond; Electron transfer; Molecule; Catalysis; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002289511,0.0001150498,0.0002946491,0.000006767871,0.0000336323,0.00001975921,0.0002150623,0.00003548284,0.0000331844],"category_scores_gemma":[0.0000811919,0.00007492449,0.0001530536,0.00008899913,0.0006262289,0.00004744432,0.00005230365,0.0001804264,5.521275e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003667848,"about_ca_system_score_gemma":0.00003906901,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001199438,"about_ca_topic_score_gemma":3.791122e-8,"domain_scores_codex":[0.9991452,0.00003138764,0.0002647907,0.0001273367,0.0002798679,0.0001514537],"domain_scores_gemma":[0.9990808,0.0001280499,0.0004896819,0.0001385207,0.00005672899,0.0001061639],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000650374,0.00006361365,0.001108663,0.00002028137,0.00001336332,0.000001522711,0.00004776799,0.0000266927,0.9965851,0.000002944793,0.001809453,0.0002555791],"study_design_scores_gemma":[0.0006534315,0.00007395723,0.0004354168,0.00005983304,0.00002570472,0.00004764398,0.00004830412,0.0007446627,0.9976033,0.00003357478,0.0001901612,0.00008398669],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9977757,0.0002463467,0.00007228033,0.001748625,0.00001503785,0.00005023835,0.00002250086,0.000004890494,0.00006435957],"genre_scores_gemma":[0.9967287,0.00003184291,0.002019835,0.001147086,0.00005436869,0.000001339628,3.905796e-7,0.000008098767,0.000008387302],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001947555,"threshold_uncertainty_score":0.3055332,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.003820582147486622,"score_gpt":0.2179529345437347,"score_spread":0.2141323523962481,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}