{"id":"W2066491907","doi":"10.1021/jp309762a","title":"Effects of Spacer Length and Terminal Group on the Crystallization and Morphology of Biscarbamates: A Longer Spacer Does Not Reduce the Melting Temperature","year":2013,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Polymer composites and self-healing","field":"Materials Science","cited_by":20,"is_retracted":false,"has_abstract":true,"ca_institutions":"Carleton University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Alkyl; Crystallization; Homologous series; Stacking; Crystallography; Hydrogen bond; Polymer chemistry; Materials science; Molecule; Tacticity; Polymer; Chemistry; Organic chemistry; Composite material; Polymerization","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002232594,0.0003347356,0.0002688058,0.0001809399,0.0001363514,0.0003031919,0.0001829588,0.0002749969,0.0008366833],"category_scores_gemma":[0.00061156,0.0002009202,0.0002701513,0.0002024297,0.0002306967,0.0003741216,0.0001966945,0.0004811704,0.000133983],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001684098,"about_ca_system_score_gemma":0.0001835872,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000577073,"about_ca_topic_score_gemma":0.0009686752,"domain_scores_codex":[0.9998131,0.00002828063,0.00002384784,0.00004532768,0.00004717794,0.00004229955],"domain_scores_gemma":[0.9994051,0.000198821,0.0001939257,0.00004367018,0.00006770262,0.00009073809],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001665843,0.00003122914,0.0002219566,0.00003989004,0.000006258588,0.00004540573,0.00003246964,0.0001261937,0.9983574,0.00001971744,0.00000995137,0.0009429746],"study_design_scores_gemma":[0.000007806319,0.0002745725,0.002387665,0.000004163954,0.0000131635,0.00004034678,0.00001602911,0.0003729395,0.9966594,0.000006309842,0.0002126616,0.000004924473],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9987096,0.000446507,0.0003033078,0.00001367279,0.000006084165,0.000008953069,0.00005979204,0.00001502268,0.0004370073],"genre_scores_gemma":[0.9981267,0.0003387782,0.001040187,0.0000207827,0.000004670441,0.00001682614,0.00008522809,0.00002213789,0.000344776],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0008366833,"threshold_uncertainty_score":0.002798915,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.005106184209183109,"score_gpt":0.2162684260138596,"score_spread":0.2111622418046765,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}