{"id":"W2066548612","doi":"10.1021/om0606035","title":"Competitive Substitution Reactions at Extracoordinate Silicon during Asymmetric Hydrosilylation","year":2006,"lang":"en","type":"article","venue":"Organometallics","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"","keywords":"Hydrosilylation; Chemistry; Alkoxy group; Yield (engineering); Stereoselectivity; Enantiomer; Catalysis; Enantiomeric excess; Molecule; Silicon; Proline; Organic chemistry; Enantioselective synthesis; Stereochemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001733778,0.0005212561,0.0002670097,0.0001535271,0.0001212197,0.0003257742,0.0003883909,0.0002581336,0.001393885],"category_scores_gemma":[0.000226339,0.0002219818,0.000203342,0.0001700145,0.00023092,0.0002954592,0.0003228025,0.0003250008,0.0005731849],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002659763,"about_ca_system_score_gemma":0.0001881346,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004697013,"about_ca_topic_score_gemma":0.001298495,"domain_scores_codex":[0.9997532,0.00003305272,0.00001683769,0.00005668863,0.00007663384,0.00006361723],"domain_scores_gemma":[0.9998655,0.00003651526,0.0000366877,0.00001908968,0.00002056522,0.00002156615],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001166481,0.00001173288,0.000139521,0.00004330522,0.000009174549,0.0001140692,0.00002959401,0.0001604839,0.9956987,0.0002389994,0.00003416036,0.003403571],"study_design_scores_gemma":[0.000008947014,0.000109254,0.0002820382,0.000001642155,0.000009098341,0.0001037965,0.00001048573,0.0003734048,0.9982988,0.00002029527,0.0007791257,0.000003154367],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9894852,0.0009270188,0.004495984,0.00004521465,0.00002034558,0.00004291801,0.0001266056,0.00006083038,0.004795959],"genre_scores_gemma":[0.9955866,0.0004704524,0.002230236,0.00001721441,0.000008245893,0.00001115369,0.00009992514,0.00001858209,0.00155758],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001393885,"threshold_uncertainty_score":0.004662991,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007814418628008617,"score_gpt":0.2103098246041979,"score_spread":0.2024954059761893,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}