{"id":"W2066586457","doi":"10.1002/jms.886","title":"MALDI‐TOF mass spectrometric analysis for the characterization of the 5,10,15,20‐tetrakis‐ (<i>m</i>‐hydroxyphenyl)bacteriochlorin (<i>m</i>‐THPBC) photoproducts in biological environment","year":2005,"lang":"en","type":"article","venue":"Journal of Mass Spectrometry","topic":"Photodynamic Therapy Research Studies","field":"Medicine","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Centre d'expertise et de recherche en infrastructures urbaines","funders":"","keywords":"Chemistry; Photobleaching; Photosensitizer; Mass spectrometry; Absorption (acoustics); Synthon; Absorption spectroscopy; Nuclear chemistry; Spectroscopy; Ultraviolet visible spectroscopy; Chromatography; Photochemistry; Stereochemistry; Organic chemistry; Fluorescence","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0003454654,0.0007960393,0.0003308588,0.0004700125,0.0002688579,0.0003153314,0.0003104918,0.0005218292,0.001694368],"category_scores_gemma":[0.0005338175,0.0002058083,0.0002659269,0.0003596703,0.0002593852,0.000381234,0.0002483312,0.0005955943,0.0006865776],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002554099,"about_ca_system_score_gemma":0.0003801502,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004630724,"about_ca_topic_score_gemma":0.0005811412,"domain_scores_codex":[0.9998135,0.00002623921,0.00001074453,0.00004843974,0.00008057757,0.00002050086],"domain_scores_gemma":[0.9996748,0.00008844775,0.00007832734,0.00001782156,0.00009351267,0.0000471047],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001820054,0.000009031937,0.0000795284,0.00002398491,0.000001807233,0.0000260909,0.00001179421,0.0000162466,0.9988549,0.00001370837,0.0000162397,0.000928534],"study_design_scores_gemma":[0.000002688462,0.0000971323,0.002636823,0.000004517435,0.000008499005,0.0002960511,0.00003039289,0.000662952,0.9952797,0.00002710306,0.0009471034,0.000006947226],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9305904,0.004125785,0.05977257,0.0002054248,0.00009358009,0.0002125728,0.001494094,0.0005663519,0.002939253],"genre_scores_gemma":[0.870383,0.005763675,0.1132969,0.0002651731,0.00004616295,0.0003562038,0.00214557,0.0001899096,0.007553447],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001694368,"threshold_uncertainty_score":0.005668283,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01966524824415804,"score_gpt":0.2673933381293928,"score_spread":0.2477280898852348,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}