{"id":"W2066586457","doi":"10.1002/jms.886","title":"MALDI‐TOF mass spectrometric analysis for the characterization of the 5,10,15,20‐tetrakis‐ (<i>m</i>‐hydroxyphenyl)bacteriochlorin (<i>m</i>‐THPBC) photoproducts in biological environment","year":2005,"lang":"en","type":"article","venue":"Journal of Mass Spectrometry","topic":"Photodynamic Therapy Research Studies","field":"Medicine","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Centre d'expertise et de recherche en infrastructures urbaines","funders":"","keywords":"Chemistry; Photobleaching; Photosensitizer; Mass spectrometry; Absorption (acoustics); Synthon; Absorption spectroscopy; Nuclear chemistry; Spectroscopy; Ultraviolet visible spectroscopy; Chromatography; Photochemistry; Stereochemistry; Organic chemistry; Fluorescence","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00208887,0.0003406541,0.001127794,0.001684614,0.0001379318,0.00003925215,0.0007094027,0.0001456146,0.001459396],"category_scores_gemma":[0.000701668,0.0001862129,0.0008267598,0.003934161,0.0002867309,0.0001897104,0.0001176335,0.000757565,0.000007919342],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000774303,"about_ca_system_score_gemma":0.0001375487,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008112002,"about_ca_topic_score_gemma":0.000007818292,"domain_scores_codex":[0.9964033,0.0002146412,0.001244942,0.0003980328,0.001104146,0.0006349667],"domain_scores_gemma":[0.997341,0.0005623674,0.001035741,0.0007083651,0.0001999038,0.0001525624],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"observational","study_design_scores_codex":[0.00105782,0.0004788843,0.04634722,0.00005089108,0.001677616,0.00001738976,0.0001268943,0.0001731032,0.9492851,0.00003271911,0.0000549295,0.0006974186],"study_design_scores_gemma":[0.002486576,0.001266779,0.7534688,0.0000680809,0.0006961238,0.00007882608,0.0002250142,0.0005126437,0.2376094,0.0001719215,0.003207557,0.0002082499],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9883908,0.001430301,0.002942956,0.005859708,0.0002019253,0.000924709,0.00007204186,0.00001212114,0.0001654312],"genre_scores_gemma":[0.9918044,0.003766841,0.002747211,0.0002018267,0.0006688185,0.00003513249,0.00001578887,0.00003304835,0.0007269274],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.7116757,"threshold_uncertainty_score":0.9994534,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01966524824415804,"score_gpt":0.2673933381293928,"score_spread":0.2477280898852348,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}