{"id":"W2066611120","doi":"10.1021/ic801349y","title":"Reactivity of a Sterically Hindered Fe(II) Thiolate Dimer with Amines and Hydrazines","year":2008,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Metalloenzymes and iron-sulfur proteins","field":"Energy","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Waterloo","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Steric effects; Trigonal bipyramidal molecular geometry; Reactivity (psychology); Denticity; Dimer; Aniline; Medicinal chemistry; Ligand (biochemistry); Isopropyl; Yield (engineering); Stereochemistry; Crystallography; Crystal structure; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002152831,0.0003036981,0.000259803,0.00006547869,0.0001385362,0.0001702295,0.000409828,0.0004600598,0.0009662556],"category_scores_gemma":[0.0001922878,0.0001518286,0.0001451036,0.00006784085,0.0002152328,0.0001441686,0.0002401464,0.0003272968,0.0002476443],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002860643,"about_ca_system_score_gemma":0.00008822313,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004702998,"about_ca_topic_score_gemma":0.0005605087,"domain_scores_codex":[0.9997867,0.00005963454,0.000008940443,0.00004330936,0.00004670539,0.00005470807],"domain_scores_gemma":[0.999918,0.00001464652,0.00001761573,0.00000975866,0.00001354879,0.00002642166],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002973279,0.00004163781,0.0002180962,0.00004808519,0.0000204219,0.00008313885,0.00004893731,0.0004537416,0.9976835,0.0001017997,0.00008633282,0.0009169583],"study_design_scores_gemma":[0.0000380702,0.0004633832,0.0008498601,0.000002536367,0.00001218304,0.0001369129,0.00002283651,0.001804881,0.9953883,0.00002940302,0.001243973,0.000007679577],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9983277,0.0003177699,0.0004415824,0.00003317689,0.000005917374,0.000007239961,0.00003095123,0.00002258019,0.0008130418],"genre_scores_gemma":[0.9981962,0.0001372284,0.0005926396,0.00002055153,0.000005102155,0.000006520854,0.00008866783,0.000006521849,0.0009465257],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009662556,"threshold_uncertainty_score":0.003232419,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01113330272752547,"score_gpt":0.1911386067335661,"score_spread":0.1800053040060407,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}