{"id":"W2066955380","doi":"10.1021/ma801826p","title":"Near-Edge X-ray Absorption Fine Structure Spectroscopy Study of the Photolytic Process in Poly(phenyl thioether) with Pendant Iron Moieties","year":2008,"lang":"en","type":"article","venue":"Macromolecules","topic":"Corrosion Behavior and Inhibition","field":"Materials Science","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Saskatchewan; Okanagan University College; University of British Columbia, Okanagan Campus; University of British Columbia","funders":"","keywords":"Thioether; Polymer; Polymer chemistry; XANES; Chemistry; Counterion; Absorption spectroscopy; Absorption (acoustics); Oxidation state; Photochemistry; Materials science; Spectroscopy; Metal; Organic chemistry; Ion","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001150492,0.0002114708,0.000111179,0.0001096189,0.0001133877,0.0001279462,0.0001192548,0.000230585,0.0009523727],"category_scores_gemma":[0.0001758953,0.0001288673,0.0001438349,0.0001119658,0.0002175697,0.000244748,0.00009211345,0.0003175506,0.0001495427],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001541237,"about_ca_system_score_gemma":0.00009155369,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003241483,"about_ca_topic_score_gemma":0.0003595959,"domain_scores_codex":[0.9999394,0.000007601461,0.00000217926,0.00001198225,0.00002378836,0.00001502541],"domain_scores_gemma":[0.9998791,0.00003999723,0.00004064737,0.00001003112,0.0000176135,0.00001251358],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002549454,0.000008930234,0.00007823129,0.00001127292,0.000001639103,0.0000328778,0.00001617625,0.00007115069,0.9991727,0.00004196517,0.000008625822,0.0005308436],"study_design_scores_gemma":[0.000003828885,0.00009046245,0.002233005,0.000001841092,0.000004045165,0.0000672621,0.00001093825,0.0005979371,0.9967037,0.00001582253,0.0002686509,0.000002555033],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982263,0.0001546459,0.001093017,0.00001267641,0.000002794329,0.000003812404,0.00002612132,0.0000136121,0.0004669525],"genre_scores_gemma":[0.9969944,0.0001457542,0.001367125,0.0000125583,0.0000024653,0.000006192931,0.00005550415,0.000009950179,0.001406038],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009523727,"threshold_uncertainty_score":0.003185987,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01190743140423676,"score_gpt":0.2452499151253239,"score_spread":0.2333424837210871,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}