{"id":"W2067056816","doi":"10.1021/ol800396v","title":"Palladium-Catalyzed Benzylic C−H Insertion of 2-Substituted <i>N</i>-Iminopyridinium Ylides","year":2008,"lang":"en","type":"article","venue":"Organic Letters","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":113,"is_retracted":false,"has_abstract":true,"ca_institutions":"Université de Montréal","funders":"","keywords":"Chemistry; Palladium; Catalysis; Aryl; Alkyl; Medicinal chemistry; Combinatorial chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001720068,0.0002261897,0.000305326,0.0001176116,0.0001377869,0.00001541048,0.0002790377,0.0001327363,0.004209668],"category_scores_gemma":[0.0003269185,0.0002410391,0.0001320853,0.000455091,0.0002039256,0.0001898652,0.00007383277,0.0001766578,0.000136781],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001733875,"about_ca_system_score_gemma":0.0001424713,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00006581008,"about_ca_topic_score_gemma":0.00001058832,"domain_scores_codex":[0.9983985,0.00003232904,0.0005002863,0.0003747922,0.000419385,0.0002747309],"domain_scores_gemma":[0.9987763,0.0001720323,0.000254509,0.0005739712,0.0001118188,0.000111364],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004809218,0.0000683109,0.00449433,0.00007780043,0.00007023454,0.00001873988,0.0002683029,0.00005148871,0.9885764,0.00009855097,0.006076777,0.0001510089],"study_design_scores_gemma":[0.0009764951,0.000005465231,0.004765546,0.00003113822,0.00006065344,0.0001297532,0.00004218441,0.000110636,0.9895268,0.00002709817,0.004061886,0.0002623455],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910435,0.00008756615,0.006217374,0.001266867,0.0003050199,0.00007633824,0.00003126181,0.000175984,0.0007960637],"genre_scores_gemma":[0.9965465,0.00004972376,0.001587375,0.0008286998,0.0002828176,0.00001316291,0.0003811065,0.00005524738,0.0002553471],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005502995,"threshold_uncertainty_score":0.9967006,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02509089202257668,"score_gpt":0.2393226007382669,"score_spread":0.2142317087156902,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}