{"id":"W2067298173","doi":"10.1021/ma010283v","title":"Effect of Fluorinated Surface-Modifying Macromolecules on the Molecular Surface Structure of a Polyether Poly(urethane urea)","year":2001,"lang":"en","type":"article","venue":"Macromolecules","topic":"Advanced Sensor and Energy Harvesting Materials","field":"Engineering","cited_by":47,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Macromolecule; Polymer; Hydrogen bond; Materials science; Chemical engineering; Polymer chemistry; Urea; Infrared spectroscopy; Dispersion (optics); Chemistry; Molecule; Organic chemistry; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002588386,0.0004681078,0.0006183377,0.00007932248,0.00007472299,0.00003526118,0.0004106906,0.0001954874,0.0001128473],"category_scores_gemma":[0.0001514699,0.0003432795,0.000172097,0.0004124487,0.0001658238,0.00006150884,0.00006883609,0.0002522619,0.00001050967],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004001868,"about_ca_system_score_gemma":0.00001311605,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001380292,"about_ca_topic_score_gemma":0.000008655612,"domain_scores_codex":[0.9980016,0.0003198185,0.0004681441,0.000323104,0.0003792953,0.0005080288],"domain_scores_gemma":[0.9987152,0.0003444218,0.0001548694,0.0006178565,0.0000735222,0.00009409604],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001409145,0.00001883783,0.0002000102,0.0001817982,0.0001200782,0.00008931629,0.0001041681,0.1089034,0.8882444,0.001278729,0.00001391092,0.000704418],"study_design_scores_gemma":[0.0005554822,0.0002821471,0.0001422351,0.0001715179,0.00005792125,0.00005395715,0.00003496918,0.001601553,0.9962128,0.000453595,0.0001156846,0.0003180872],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9950093,0.001193799,0.001301748,0.00005213686,0.0002514812,0.0002707109,0.0001080825,0.000230729,0.001581979],"genre_scores_gemma":[0.9984702,0.00008792921,0.001161158,0.00003771548,0.00003230323,0.000003767582,0.00002778337,0.0001241944,0.00005490323],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1079684,"threshold_uncertainty_score":0.999902,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007578539538394863,"score_gpt":0.2305097263574666,"score_spread":0.2229311868190717,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}