{"id":"W2067391353","doi":"10.1002/pat.1773","title":"Kinetic study of polysulfide‐acrylate click reaction by DEA and DMA","year":2011,"lang":"en","type":"article","venue":"Polymers for Advanced Technologies","topic":"Click Chemistry and Applications","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Research Council Canada","keywords":"Polysulfide; Acrylate; Curing (chemistry); Catalysis; Materials science; Amine gas treating; Kinetics; Activation energy; Polymer chemistry; Stoichiometry; Chemical engineering; Copolymer; Chemistry; Polymer; Organic chemistry; Physical chemistry; Composite material","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00077008,0.0006821273,0.0007106974,0.0002878346,0.0001650167,0.0002737958,0.0003009745,0.0002916032,0.001608312],"category_scores_gemma":[0.0008096536,0.0002787611,0.0003246633,0.0003700554,0.0001957736,0.0005820501,0.0001801944,0.0006982231,0.000834091],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002933264,"about_ca_system_score_gemma":0.0002183584,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005419147,"about_ca_topic_score_gemma":0.0005393416,"domain_scores_codex":[0.9996345,0.00005949249,0.00002419221,0.00008072173,0.0001133626,0.00008771792],"domain_scores_gemma":[0.999655,0.0001393155,0.00008361881,0.00002756943,0.00004930213,0.00004510402],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002255321,0.00004594354,0.0002097218,0.0001376138,0.00002061289,0.00006095086,0.00008125514,0.000459041,0.9947314,0.0004004403,0.00009416103,0.003533304],"study_design_scores_gemma":[0.000007985682,0.0001203629,0.0005753434,0.000004447648,0.00001054769,0.00005173555,0.000007941678,0.001605974,0.9965227,0.00004062927,0.001043419,0.000008963725],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9697881,0.005259759,0.01911686,0.0001088598,0.0000521247,0.0001059574,0.0004535248,0.0002175463,0.00489715],"genre_scores_gemma":[0.9889627,0.0019062,0.004203251,0.00002213997,0.0000116276,0.00006733156,0.0002269161,0.0000439435,0.004555861],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001608312,"threshold_uncertainty_score":0.005380332,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0201344975917808,"score_gpt":0.2571423399670891,"score_spread":0.2370078423753083,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}