{"id":"W2067724200","doi":"10.1021/jo9021088","title":"Effect of Alkyl Substituents on Photorelease from Butyrophenone Derivatives","year":2010,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Photochromic and Fluorescence Chemistry","field":"Materials Science","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"","keywords":"Chemistry; Intersystem crossing; Intramolecular force; Photochemistry; Flash photolysis; Moiety; Isopropyl; Acetonitrile; Cyclohexane; Photodissociation; Intramolecular reaction; Medicinal chemistry; Stereochemistry; Reaction rate constant; Organic chemistry; Singlet state; Excited state; Kinetics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002205805,0.0006652783,0.0002247971,0.0001468665,0.0001610893,0.0002353628,0.0003453447,0.0003154023,0.003333786],"category_scores_gemma":[0.0005448099,0.0002226474,0.0001949542,0.0002463005,0.0001984673,0.0003764248,0.0001779113,0.0006987766,0.000625962],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003274831,"about_ca_system_score_gemma":0.0003045009,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009310432,"about_ca_topic_score_gemma":0.001528421,"domain_scores_codex":[0.9998418,0.00002199616,0.00001331809,0.00002817269,0.00003067612,0.00006395667],"domain_scores_gemma":[0.9995418,0.0001791221,0.0001111073,0.00004074689,0.00005091176,0.00007647208],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003609415,0.00003854024,0.00008965474,0.0001098499,0.00001040224,0.0001662323,0.00003976463,0.0001779588,0.9971054,0.0001114303,0.00006240386,0.001727243],"study_design_scores_gemma":[0.00001825634,0.0003966526,0.0008220683,0.00000764156,0.00001316527,0.0000755802,0.00001685826,0.0001860604,0.9972042,0.0000209843,0.001231717,0.000006709455],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952024,0.001126829,0.0008393144,0.00009049208,0.00004597073,0.00002312202,0.0001275027,0.00007317594,0.002471196],"genre_scores_gemma":[0.9943132,0.001829723,0.001111526,0.00009908684,0.00001344057,0.00003116737,0.0002510236,0.00006000133,0.002290842],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003333786,"threshold_uncertainty_score":0.01115263,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.0041600685032402,"score_gpt":0.2225768065240694,"score_spread":0.2184167380208292,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}